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| 1 | Rapid determination of pharmaceuticals from multiple therapeutic classes in wastewater by solid-phase extraction and ultra-performance liquid chromatography tandem mass spectrometry显示文摘A new analytical method utilizing ultra-performance liquid chromatography (UPLC) tandem mass spectrometry (MS/MS) has been developed to determine 16 pharmaceuticals from 8 therapeutic classes in wastewater: bezafibrate, clofibric acid, carbamazepine, caffeine, chloramphenicol, diclofenac, gemfibrozil, indomethacin, ketoprofen, mefenamic acid, metoprolol, nalidixic acid, N,N-diethyl-metatoluamide, propranolol, sulpiride and trimethoprim. Key parameters of MS/MS, UPLC and solid phase extraction (SPE) were optimized. In general, recovery of target pharmaceuticals was over 70% for the wastewater effluent samples and 50% for the influent samples. The effects of matrix suppression, loss during the pretreatment as well as instrument variability were successfully corrected by two internal standards, and acceptable relative recovery was obtained. Target compounds were quantitatively analyzed using multiple reaction monitoring (MRM) mode, and the detection limits ranged from 0.3 to 20 ng/L. A detailed study, matrix effect in effluent wastewater was also present. The method was applied to detecting pharmaceuticals in the wastewater from three wastewater treatment plants (WWTPs) in Beijing, China and the results demonstrated that most target compounds were detectable in both the influent and effluent, with the mean concentrations ranging from 20.5 to 5775.6 ng/L and 4.6 to 418.6 ng/L, respectively. | SUI Qian HUANG Jun DENG ShuBo YU Gang | 2009 | Chinese Science Bulletin2009，54，24： | 16 |
| 2 | Contaminants of emerging concern in landfill leachate in China:A review显示文摘This review paper summarizes the occurrence,removal and ecological risk of contaminants of emerging concern(CEC)reported in landfill leachate in China since 1996(43 studies in 10 regions).Results show that many more studies are conducted in developed southeastern China than in developing western and northeastern regions in China.Phthalate esters(PAEs,with 15 studies)and pharmaceuticals and personal care products(PPCPs,with 13 studies)are the two most frequently studied CEC classes.Concentrations of nine CECs classes were in a wide range from 0.03(organochlorine pesticides)to approximately 4500 mg/L(alkylphenol polyethoxylates/bisphenol analog).Meanwhile,concentrations of CEC compounds range from below detection limit(e.g.doxycycline)to approximately 4500 mg/L(bisphenol A).Several PAEs(diethyl phthalate,di-n-butyl phthalate,and di(2-ethylhexyl)phthalate)and PPCPs(diclofenac and gemfibrizol)have significant variation between sampling sites.Typically,advanced treatment processes can achieve higher removal efficiencies of CEC compounds from landfill leachate compared with conventional treatment processes.Furthermore,environmental risk assessments of CEC compounds in treated landfill leachate using a risk quotient method show that 2(substituted)polycyclic aromatic hydrocarbons(sPAHs)(benzo(a)anthracene and benzo(b)fluoranthene),2 PPCPs(bezafibrate and sulfapyridine),g-hexachlorocyclohexane,and bisphenol A pose high risk.The importance of monitoring and potential risks of CECs in the leachate to vicinity aquatic environment cross China is addressed. | Chengdu Qi Jun Huang Bin Wang Shubo Deng Yujue Wang Gang Yu | 2018 | Emerging Contaminants2018，4，1： | 10 |
| 3 | Activated carbons and amine-modified materials for carbon dioxide capture- a review显示文摘 | Zhenhe CHEN Shubo DENG Haoran WEI Bin WANG Jun HUANG Gang YU | 2013 | Frontiers of Environmental Science & Engineering2013，7，3： | 9 |
| 4 | Rapid removal of bisphenol A on highly ordered mesoporous carbon显示文摘Bisphenol A (BPA) is of global concern due to its disruption of endocrine systems and ubiquity in the aquatic environment.It is important,therefore,that efforts are made to remove it from the aqueous phase.A novel adsorbent,mesoporous carbon CMK-3,prepared from hexagonal SBA-15 mesoporous silica was studied for BPA removal from aqueous phase,and compared with conventional powdered activated carbon (PAC).Characterization of CMK-3 by transmission electron microscopy (TEM),X-ray diffraction,and nitrogen adsorption indicated that prepared CMK-3 had an ordered mesoporous structure with a high specific surface area of 920 m 2 /g and a pore-size of about 4.9 nm.The adsorption of BPA on CMK-3 followed a pseudo second-order kinetic model.The kinetic constant was 0.00049 g/(mg·min),much higher than the adsorption of BPA on PAC.The adsorption isotherm fitted slightly better with the Freundlich model than the Langmuir model,and adsorption capacity decreased as temperature increased from 10 to 40°C.No significant influence of pH on adsorption was observed at pH 3 to 9;however,adsorption capacity decreased dramatically from pH 9 to 13. | Qian Sui Jun Huang Yousong Liu Xiaofeng Chang Guangbin Ji Shubo Deng Tao Xie Gang Yu | 2011 | Journal of Environmental Sciences2011，23，2： | 8 |
| 5 | Removal of pharmaceutical and personal care products by sequential ultraviolet and ozonation process in a full-scale wastewater treatment plant显示文摘在市政的废水处理植物(WWTP ) 的适当先进处理过程的应用程序就新兴的沾染物的消除而言成为了一个重要问题,例如药品、个人的照顾产品(PPCP ) 。在现在的学习,属于不同的治疗学的班由的 13 PPCP 的移动顺序紫外(紫外) 并且在在北京的照原尺寸的 WWTP 的 ozonation 过程在十个月的功课上被调查。大多数目标 PPCP 有效地被移开,并且单个 PPCP 的中部的移动效率,从 13% ~ 89%,依赖于他们有分子的臭氧的反应率常数。在一样的 PPCP 的移动效率的显著变化在不同采样运动被观察。不过,顺序紫外并且仍然在照原尺寸的 WWTP 成为重要贡献到大多数 PPCP 的全部的消除的 ozonation 过程,由由生物学的处理补偿 PPCP 的差或变动的移动性能处理。 | Qian SU Jun HUANG Shuguang LU Shubo DENG Bin WANG Wentao ZHAO Zhaofu QIU Gang YU | 2014 | Frontiers of Environmental Science & Engineering2014，8，1： | 6 |
| 6 | Addressing the environmental risk of persistent organic pollutants in China显示文摘坚持的器官的污染物质(流行音乐) 上的斯德哥尔摩习惯在 2001 被采用。今年是习惯的采纳的第 10 周年。直到现在, 22 化学药品或化学范畴在斯德哥尔摩习惯作为流行音乐被列出了。流行音乐研究中心在大会被采用的一样的年里在清华大学里被建立。在最后十年里,许多工作被中国研究人员做了在中国理解流行音乐的环境风险。这篇文章试图在探讨流行音乐的环境风险考察我们的流行音乐研究中心和一些另外的中国研究人员研究的最近的研究进步,包括屏蔽的优先级和流行音乐的库存学习,流行音乐监视并且当模特儿污染和暴露,和环境风险评价并且流行音乐当模特儿。尽管在探讨流行音乐的环境风险的大进展在最近的年里被做了,我们仍然正在面对许多问题,例如在对流行音乐的环境风险评价的数据缺乏和无常。流行音乐混合物的效果上的学习在它的幼年期,当前,流行音乐被对单个化学药品的风险评价通常从法律观点估计。这些问题应该被进一步的努力很好处理。进一步的研究应该也在未来被拿由考虑在气候过程和流行音乐之间的联合动力学的方面学习流行音乐的环境风险。这听起来科学, riskbased 信息能支持试图有效地最小化流行音乐的风险水平的决策。 | Bin WANG Jun HUANG Shubo DENG Xiaoling YANG Gang YU | 2012 | Frontiers of Environmental Science & Engineering2012，6，1： | 5 |
| 7 | Fate and removal of typical pharmaceutical and personal care products in a wastewater treatment plant from Beijing: a mass balance study显示文摘在废水处理植物(WWTP ) 的药品和个人照顾产品(PPCP ) 的命运和移动在最后十年期间收到了大注意。有关在水阶段的集中的众多的数据能在文学被发现,从象联系集体平衡计算一样的污泥的然而相应的数据很被限制。在现在的学习, 9 PPCP 的吸附并且溶解的集中在中国北京在 WWTP 的每个单位被调查。基于集体平衡,相对集体分发和每目标混合物的移动效率的计算在每个过程被获得。进入 WWTP 的 PPCP 的数量从 12 g 僚?? ??????丠??‰?????????瀠潲楰湯瑡?????????????????????????吗????丠??‰?????????????????獩灯潲祰???? | Jie GAO Jun HUANG Weiwei CHEN Bin WANG Yujue WANG Shubo DENG Gang YU | 2016 | Frontiers of Environmental Science & Engineering2016，10，3： | 4 |
| 8 | Pay special attention to the transformation products of PPCPs in environment显示文摘Pharmaceuticals and personal care products(PPCPs)have received increasing attention.However,their transformation products(TPs)and metabolites,sometimes even with environmental concentration and/or toxicity higher than their parent compounds,received attention far from enough.This study gives useful insight on the occurrence,fate and toxicity of PPCP TPs or metabolites in WWTPs,surface water and even drinking water,highlighting the necessity of studying the PPCP TPs formation,occurrence,toxicity and environment risk,and further evaluating the environmental risk caused by PPCPs comprehensively. | Lina Yin Bin Wang Honglin Yuan Shubo Deng Jun Huang Yujue Wang Gang Yu | 2017 | Emerging Contaminants2017，3，2： | 4 |
| 9 | Electrochemical oxidation of 1H,1H,2H,2H-perfluorooctane sulfonic acid(6:2 FTS) on DSA electrode:Operating parameters and mechanism显示文摘The 6:2 FTS was the substitute for perfluorooctane sulfonate(PFOS) in the chrome plating industry in Japan. Electrochemical oxidation of 6:2 FTS was investigated in this study. The degradabilities of PFOS and 6:2 FTS were tested on the Ti/SnO2–Sb2O5–Bi2O3anode. The effects of current density,potential,and supporting electrolyte on the degradation of 6:2 FTS were evaluated. Experimental results showed that 6:2 FTS was more easily degraded than PFOS on the Ti/SnO2–Sb2O5–Bi2O3anode. At a low current density of 1.42 mA/cm2,6:2 FTS was not degraded on Ti/SnO2–Sb2O5–Bi2O3,while the degradation ratio increased when the current density ranged from 4.25 to 6.80 mA/cm2. The degradation of 6:2 FTS at current density of 6.80 mA/cm2 followed pseudo first-order kinetics with the rate constant of 0.074 hr-1. The anodic potential played an important role in the degradation of 6:2 FTS,and the pseudo first-order rate constants increased with the potential. The surface of Ti/SnO2–Sb2O5–Bi2O3was contaminated after electrolysis at constant potential of 3 V,while the fouling phenomenon was not observed at 5 V. The fouled anode could be regenerated by incinerating at 600°C. The intermediates detected by ultra-performance liquid chromatography coupled with a triple-stage quadrupole mass spectrometer(UPLC–MS/MS) were shorter chain perfluorocarboxylic acids. The 6:2 FTS was first attacked by hydroxyl radical,and then formed perfluorinated carboxylates,which decarboxylated and removed CF2 units to yield shorter-chain perfluorocarboxylic acids. | Qiongfang Zhuo Xiang Li Feng Yan Bo Yang Shubo Deng Jun Huang Gang Yu | 2014 | Journal of Environmental Sciences2014，26，8： | 4 |
| 10 | Selective sorption of perfluorooctane sulfonate on molecularly imprinted polymer adsorbents显示文摘Perfluorooctane sulfonate(PFOS),as a potential persistent organic pollutant,has been widely detected in water environments,and has become a great concern in recent years.PFOS is very stable and difficult to decompose using conventional techniques.Sorption may be an attractive method to remove it from water.In this study,the molecularly imprinted polymer(MIP)adsorbents were prepared through the polymerization of 4-vinylpyridine under different preparation conditions in order to remove perfluorooctane sulfonate(PFOS)from water.The MIP adsorbents using perfluorooctanoic acid(PFOA)as the template had good imprinting effects and could selectively remove PFOS from aqueous solution.The sorption behaviors including sorption kinetics,isotherms,and effect of pH,salt,and competitive anions were investigated.Experimental results showed that the sorption of PFOS on the MIP adsorbents was very fast,pHdependent,and highly selective.The achieved fast sorption equilibrium within 1 h was attributed to the surface sorption on the fine adsorbents.The sorption isotherms showed that the sorption selectivity of PFOS on the MIP adsorbents decreased at high PFOS concentrations,which may be due to the double-layer sorption and the formation of PFOS micelles on the sorbent surface.The sorption of PFOS on the MIP adsorbents was mainly dominated by the electrostatic interaction between the protonated vinylpyridine on the adsorbent surface and the anionic PFOS.The prepared MIP adsorbents can potentially be applied in water and wastewater treatment for selective removal of PFOS. | Shubo DENG Danmeng SHUAI Qiang YU Jun HUANG Gang YU | 2009 | Frontiers of Environmental Science & Engineering2009，3，2： | 4 |
| 11 | A cross-linked fluorinated poly (aryl ether oxadiazole) s using a thermal cross-linking for anion exchange membranes显示文摘 | Cunpu Li Shubo Wang Wenpin Wang Xiaofeng Xie Yafei Lv Changsheng Deng | 2013 | International Journal of Hydrogen Energy2013，，： | 3 |
| 12 | Effect of co-existing organic compounds on adsorption of perfluorinated compounds onto carbon nanotubes显示文摘共存的有机化合物可以在水的环境影响 perfluorinated 混合物(陆军) 和碳 nanotubes 的吸附。 perfluorooctane sulfonate ( PFOS )的吸附, perfluorooctane 酸( PFOA ), perfluorobutane sulfonate ( PFBS ),和 perfluorohexane sulfonate ( PFH x S )在太古的多围的碳 nanotubes ( MWCNTs-Pri )上, carboxyl functionalized MWCNT ( MWCTNs-COOH ),并且氢氧根 functionalized MWCNT ( MWCNT --哦)面对腐殖的酸,1萘粉,酚,和安息香的酸被学习。PFOS 的吸附动力学被 pseudo-second-order 模型描述很好,吸着平衡几乎在 24 h 以内被到达。PFOS 吸附上的共存的有机化合物的效果跟随了腐殖的酸的减少的顺序 >1 萘粉 > 安息香的酸 > 酚。PFOS 的吸附的数量面对共存显著地减少了或预装腐殖的酸,和两个吸附精力,导致 PFOS 的减少并且三 MWCNT 上的有效吸附地点减少了吸附。与增加 pH,由三 MWCNT 的 PFOS 移动面对腐殖的酸和酚减少了。MWCNT 上的不同陆军的吸附的数量在 PFBS x S < PFOA < PFOS。起始的集中的增加和共存的有机化合物的芳香的戒指的数字在 MWCNT 上压制了 PFOS 吸附。 | Shubo DENG Yue BEI Xinyu LU Ziwen DU Bin WANG Yujue WANG Jun HUANG Gang YU | 2015 | Frontiers of Environmental Science & Engineering2015，9，5： | 3 |
| 13 | Occurrence and discharge of pharmaceuticals and personal care products in dewatered sludge from WWTPs in Beijing and Shenzhen显示文摘This study mainly focused on the occurrence of pharmaceutical and personal care products(PPCPs)in sewage dewatered sludge and their discharges through sludge disposal from wastewater treatment plants(WWTPs).The data were obtained and calculated from seven PPCPs in dewatered sludge collected from 12WWTPs in two typical cities,Beijing and Shenzhen in China.Four of seven PPCPs,diclofenac acid,carbamazepine,mefenamic acid and N,N-diethyl-m-toluamide were detectable in dewatered sludge from Beijing and Shenzhen with concentration up to 4240,11,060,92 and 219μg/kg respectively.While,the other three compounds,trimethoprim,chloramphenicol and bezafibrate were not detected in collected samples from these two cities.The highest discharge of diclofenac acid and carbamazepine were 1023 g/d and 494 g/d respectively.In addition,the total discharge of these four detected PPCPs from each plant ranged from 5 to 1092 g/d in Beijing and 4e497 g/d in Shenzhen.Thus,PPCP discharge through sludge disposal cannot be neglected,and further research on transfer of PPCPs during sludge disposal onto agriculture land and influence of sludge application is required and essential. | Rui Dong Gang Yu Yuntao Guan Bin Wang Jun Huang Shubo Deng Yujue Wang | 2016 | Emerging Contaminants2016，2，1： | 2 |
| 14 | Reverse Engineering Analysis Based on Differential Fault Analysis Against Secret S- boxes显示文摘To evaluate the security of cipher algorithms with secret operations, we built a new reverse engineering analysis based on Differential Fault Analysis (DFA) to recover the secret S-boxes in Secret Private Network (SPN) and Feistel structures, which are two of the most typical structures in block ciphers. This paper gives the general definitions of these two structures and proposes the reverse engineering analysis of each structure. Furthermore, we evaluate the complexity of the proposed reverse analyses and theoretically prove the effectiveness of the reverse method. For the Twofish-like and AES-like algorithms, the experimental results verify the correctness and efficiency of the reverse analysis. The proposed reverse analysis can efficiently recover the secret S-boxes in the encryption algorithms with SPN and Feistel structures. It can successfully recover the Twofish-like algorithm in 2.3 s with 256 faults and the AES-like algorithm in 0.33 s with 23 faults. | Tang Ming Qiu Zhenlong Deng Hui Liu Shubo Zhang Huanguo | 2012 | China Communications2012，9，10： | 2 |
| 15 | Characterization of PEI-modified biomass and biosorption of Cu(II), Pb(II) and Ni(II)显示文摘 | Shubo Deng Yen-Peng Ting | 2005 | Water Research2005，，10： | 1 |
| 16 | Destabi]ization of oil droplets in produced water from ASP flooding显示文摘 | Yu Gang Jiang Zhanpeng | 2005 | Colloids and Surfaces A:Physieochem Eng Aspects2005，，252： | 1 |
| 17 | Highly ac- tive and stable Ni-Fe bimetal prepared by ball milling for catalytic hydrodechlorination of 4-chlorophenol 显示文摘 | Xu Fuyuan Deng Shubo Xu Jie | 2012 | Environ Sci Technol2012，46，8： | 1 |
| 18 | Effects of alkaline/surfactant/polymer on stability of oil droplets in produced water from ASP flooding显示文摘 | Deng Shubo Bai Renbi Chen J Paul | 2002 | Colloids and Surfaces A:Physieochem Eng Aspects2002，211，23： | 1 |
| 19 | Destabilization of oil droplets in produced water from ASP flooding显示文摘 | Shubo Deng Gang Yu Zhanpeng Jiang Ruiquan Zhang Yen Peng Ting | 2004 | Colloids and Surfaces A: Physicochemical and Engineering Aspects2004，，： | 1 |
| 20 | Behaviors and mechanisms of copper adsorption on hydrolyzed poly- acrylonitrile fibers 显示文摘 | Deng Shubo Bai Renbi Chen J P | 2003 | Journal of Colloid and Interface Science2003，260，2： | 1 |
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