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| 1 | Superhydrophobic fluoride conversion coating on bioresorbable magnesium alloy——fabrication,characterization,degradation and cytocompatibility with BMSCs显示文摘A micro-nano structure CaF_(2)chemical conversion layer was prepared on fluoride-treated AZ31 alloy,then the composite fluoride conversion film(CaF_(2)/MgF_(2))was modified by stearic acid(SA)and fabricated a superhydrophobic surface.The fluoride-treated magnesium,fluoride conversion film and superhydrophobic coating were characterized by SEM,EDS,XRD and FTIR.The properties of coatings1 adhesion and corrosion resistance were evaluated via tape test and electrochemical measurement.The cytocompatibility of the MgF_(2),CaF_(2)and superhydrophobic CaF_(2)/SA surface was investigated with bone marrow-derived mesenchymal stem cells(BMSCs)by direct culture for 24 h.The results showed that the superhydrophobic fluoride conversion coating composed of inner MgF_(2)layer and the outer CaF_(2)/SA composite layer had an average water contact angle of 152°.SA infiltrated into the micro-nano structure CaF_(2)layer and formed a strong adhesion with CaF_(2)layer.Furthermore,the super-hydrophobic coating showed higher barrier properties and corrosion resistance compared with the fluoride conversion film and fluoride-treated AZ31 alloy.The BMSC adhesion test results demonstrated MgF_(2)CaF_(2)and CaF_(2)/SA coatings were all nontoxic to BMSC.At the condition of in direct contact with cells,MgF_(2)showed higher cell density and enhanced the BMSCs proliferation,while CaF_(2)and CaF_(2)/SA coating showed no statistically difference in cell density compared with glass reference but the CaF_(2)and CaF_(2)/SA coating were not conducive to BMSCs adhesion. | Chunyan Zhanga Shiyu Zhang Dongwei Sun Jiajia Lin Fancheng Meng Huinan Liu | 2021 | Journal of Magnesium and Alloys2021,9,4: | 3 |
| 2 | Effect of burn injury on apoptosis and expression of apoptosis-related genes/proteins in skeletal muscles of rats显示文摘 | Hongjie Duan Jiake Chai Zhiyong Sheng Yongming Yao Huinan Yin Liming Liang Chuanan Shen Jing Lin | 2009 | Apoptosis2009,,1: | 2 |
| 3 | High-performance Li-ion capacitor based on black-TiO2-x/graphene aerogel anode and biomass-derived microporous carbon cathode显示文摘Lithium-ion capacitor (LIC) has been regarded as a promising energy storage system with high powder density and high energy density.However,the kinetic mismatch between the anode and the cathode is a major issue to be solved.Here we report a high-performance asymmetric LIC based on oxygen-deficient black-TiO2-x/graphene (B-TiO2-x/G) aerogel anode and biomass derived microporous carbon cathode.Through a facile one-pot hydrothermal process,graphene nanosheets and oxygen-vacancy-rich porous B-TiO2-x/G nanosheets were self-assembled into three-dimensional (3D) interconnected B-TiO2-x/G aerogel.Owing to the rich active sites,high conductivity and fast kinetics,the B-TiO2-x/G aerogel exhibits remarkable reversible capacity,high rate capability and long cycle life when used as anode material for lithium ion storage.Moreover,density functional theory (DFT) calculation reveals that the incorporation of graphene nanosheets can reduce the energy barrier of Li^+ diffusion in B-TiO2-x.The asymmetric LIC based on B-TiO2-x/G aerogel anode and naturally-abundant pine-needles derived microporous carbon (MPC) cathode work well within a large voltage window (1.0-4.0 V),and can deliver high energy density (166.4 Wh·kg^-1 at 200 mA·g^-1),and high power density (7.9 kW·kg^-1 at 17.1 Wh·kg^-1).Moreover,the LIC shows a high capacitance retention of 87% after 3,000cycles at 2,000 mA·g^-1.The outstanding electrochemical performances indicate that the rationally-designed LICs have promising prospect to serve as advanced fast-charging energy storage devices. | Guoyin Zhu Lianbo Ma Huinan Lin Peiyang Zhao Lei Wang Yi Hu Renpeng Chen Tao Chen Yanrong Wang Zuoxiu Tie Zhong Jin | 2019 | Nano Research2019,12,7: | 2 |
| 4 | MINITYPE MACHINING SYSTEM FOR DIAMOND LAPPING & POLISHING BY USING BRUSHLESS DIRECT CURRENT MOTOR AS PRECISE SPINDLE显示文摘A minitype precise spindle system which can machine precisely and stably in the process of diamond lapping and polishing is designed.In such minitypc spindle system,the brushless DC spindle motor is used to drive the lapping finish table,which is built with fluid dynamic bearings. Some measures have been taken to make the lapping system dynamic balance,and a serve controller which can adjust the speed of motor from 1200 r/rain to 5400 r/min is designed.Experiments show that the spindle system is reliable and stable for diamond polishing,and the detection results by atomic force microscope(AFM) show that the surfaces of diamond edge′s R= is 6.725 nm and whole diamond average R,is 3.25 nm. | FU Huinan CHEN Dongsheng ZHAO Yong LIN Binquan | 2008 | Chinese Journal of Mechanical Engineering2008,21,2: | 1 |
| 5 | In vitro evaluation of degradation,cytocompatibility and antibacterial property of polycaprolactone/hydroxyapatite composite coating on bioresorbable magnesium alloy显示文摘Polycaprolactone/hydroxyapatite(PCL/HA)composite coating was fabricated by a combination of hydrothermal and dipping methods to delay the degradation of Mg alloy AZ31 as bioresorbable materials.The PCL/HA coating was composed of nano rod-shape HA crystals and PCL filled in the space of HA crystals.Compared with the single HA coating,the binding strength between the PCL/HA composite coating and Mg alloy was obviously improved and the PCL/HA coating still adhered to the surface of AZ31 substrate even after 38 days of immersion.The electrochemical corrosion rate of HA coated sample was reduced by ten times after being filled by PCL.The electrochemical impedance spectroscopy(EIS)and immersion test results showed that the PCL/HA composite coating could provide a more effective barrier for Mg substrate than the HA coating alone.The cytocompatibility and the antibacterial property of HA coating and PCL/HA coating were evaluated by culturing with bone marrow-derived mesenchymal stem cells(BMSCs)and methicillin-resistant staphylococcus aureus(MRSA)for 24 h under direct culture conditions,respectively.The PCL/HA composite coating showed better BMSC cell compatibility,more suitable for BMSC adhesion than HA coating alone and showed a potential application prospect as a biological materials.However,from the perspective of clinical applications,the antibacterial property of PCL/HA composite coating needs to be further improved. | Zhang Chunyan Cheng Lan Lin Jiajia Sun Dongwei Zhang Jun Liu Huinan | 2022 | Journal of Magnesium and Alloys2022,10,8: | 1 |
| 6 | Atomically Dispersed Ruthenium Catalysts with Open Hollow Structure for Lithium-Oxygen Batteries显示文摘Lithium–oxygen battery with ultrahigh theoretical energy density is considered a highly competitive next-generation energy storage device,but its practical application is severely hindered by issues such as difficult decomposition of discharge products at present.Here,we have developed N-doped carbon anchored atomically dispersed Ru sites cathode catalyst with open hollow structure(h-RuNC)for Lithium–oxygen battery.On one hand,the abundance of atomically dispersed Ru sites can effectively catalyze the formation and decomposition of discharge products,thereby greatly enhancing the redox kinetics.On the other hand,the open hollow structure not only enhances the mass activity of atomically dispersed Ru sites but also improves the diffusion efficiency of catalytic molecules.Therefore,the excellent activity from atomically dispersed Ru sites and the enhanced diffusion from open hollow structure respectively improve the redox kinetics and cycling stability,ultimately achieving a high-performance lithium–oxygen battery. | Xin Chen Yu Zhang Chang Chen Huinan Li Yuran Lin Ke Yu Caiyun Nan Chen Chen | 2024 | Nano-Micro Letters2024,16,2: | 0 |
| 7 | A portable device for studying the effects of fluid flow on degradation properties of biomaterials inside cell incubators显示文摘A portable device was designed and constructed for studying the properties of biomaterials in physiologically relevant fluids under controllable flow conditions that closely simulate fluid flow inside the body.The device can fit entirely inside a cell incubator;and,thus,it can be used directly under standard cell culture conditions.An impedance-driven pump was built in the sterile flow loop to control the flow rates of fluids,which made the device small and portable for easy deployment in the incubator.To demonstrate the device functions,magnesium(Mg)as a representative biodegradable material was tested in the flow device for immersion degradation under flow versus static conditions,while the flow module was placed inside a standard cell incubator.The flow rate was controlled at 0.1760.06 ml/s for this study;and,the flow rate is adjustable through the controller module outside of incubators for simulating the flow rates in the ranges of blood flow in human artery(0.050.43 ml/s)and vein(0.020.08 ml/s).Degradation of Mg under flow versus static conditions was characterized by measuring the changes of sample mass and thickness,and Mg2t ion concentrations in the immersion media.Surface chemistry and morphology of Mg after immersion under flow versus static conditions were compared.The portable impedance-driven flow device is easy to fit inside an incubator and much smaller than a peristaltic pump,providing a valuable solution for studying biomaterials and implants(e.g.vascular or ureteral stents)in body fluids under flow versus static conditions with or without cells. | Wensen Jiang Jiajia Lin Alex H.Chen Jianwei Pan Huinan Liu | 2019 | Regenerative Biomaterials2019,6,1: | 0 |