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| 1 | Metal-organic framework-derived Fe/Cu-substituted Co nanoparticles embedded in CNTs-grafted carbon polyhedron for Zn-air batteries显示文摘Metal-organic frameworks(MOFs)and MOF-derived materials have attracted great attention as alternatives to noble-metal based electrocatalysts owing to their intriguing structure properties,especially for high efficiency and stable oxygen reduction reaction(ORR).Herein,we employed a one-pot reaction to make a multimetal(Fe,Co,Cu,and Zn)mixed zeolitic imidazolate framework(MM-ZIF)via adopting a simple in situ redox reaction.Further pyrolysis of the target MM-ZIF,a highly porous carbon polyhedron(FC-C@NC)grafted with abundant carbon nanotubes was obtained,in which ultrasmall Co nanoparticles with partial lattice sites substituted by Fe and Cu were embedded.The obtained FC-C@NC possessed large surface area,highly porous structure,widely-spread metal active sites,and conductive carbon frameworks,contributing to outstanding ORR activity and long-term stability.It displayed superior tolerance to methanol crossover and exceeded the commercial Pt/C catalyst and most previously reported non-noble-metal catalysts.Impressively,the as-produced FC-C@NC-based zinc-air battery afforded an open-circuit potential of 1.466 V,a large specific capacity of 659.5 mAh/g,and a high gravimetric energy density of 784.3 Wh/kgZn,significantly outperforming the Pt/C-based cathode. | Kexin Zhang Yelong Zhang Qinghua Zhang Zibin Liang Lin Gu Wenhan Guo Bingjun Zhu Shaojun Guo Ruqiang Zou | 2020 | Carbon Energy2020，2，2： | 7 |
| 2 | Metal-organic framework based nanomaterials for electrocatalytic oxygen redox reaction显示文摘Due to the severe environmental issues, many advanced technologies, typically fuel cells and metal-air batteries have aroused widespread concerns and been intensively studied in recent years. However, oxygen redox reactions including oxygen evolution reaction(OER) and oxygen reduction reaction(ORR) as the core reactions suffer from sluggish kinetics of the multiple electron transfer process. Currently, Pt, RuO_2, and IrO_2 are considered to be the benchmark catalysts for ORR and OER, but their high price, scarcity and instability hinder them from large-scale application. To overcome these limits, exploring alternative electrocatalysts with low cost, high activity, long-term stability, and earth-abundance is of extreme urgency. Metal-organic frameworks(MOFs) are a family of inorganic-organic hybrid materials with high surface areas and tunable structures, making them proper as catalyst candidates. Herein, the recent progress of MOFs and MOF-derived materials for ORR and OER is systematically reviewed, and the relationship between compositions and electrochemical performance is discussed. It is expected that this review can be helpful for the future development of related MOF-based materials with excellent electrochemical performance. | Kexin Zhang Wenhan Guo Zibin Liang Ruqiang Zou | 2019 | Science China Chemistry2019，62，4： | 6 |
| 3 | Highly efficient K-Fe/C catalysts derived from metal-organic frameworks towards ammonia synthesis显示文摘Fe-based catalysts have been discovered as the best elementary metal-based heterogeneous catalysts for the ammonia synthesis in industrial application during the last century.Herein,a novel and scalable strategy is developed to prepare the K-promoted Fe/C catalyst with extremely high Fe loading (> 50 wt.%) through pyrolysis of the Fe-based metal-organic framework (MOF) xerogel.The obtained K-Fe/C catalysts exhibited superior activity and stability towards ammonia synthesis.The weight-specific reaction rate of Fe/C with K2O as promoter can achieve 12.4 mmol·g-1·h-1 at 350 ℃ and 30.4 mmol·g-1·h-1 at 400 ℃,approximately four and two times higher than that of the commercial fused-iron catalyst (3.4 mmol·g-1·h-1 at 350 ℃ and 16.7 mmol·g-1·h-1 at 400 ℃) under the same condition,respectively.The excellent performance of K-Fe/C can be ascribed to the inherited structure derived from the metal-organic frame precursors and the promotion of potassium,which can modify the binding energy of reactant molecules on the Fe surface,transfer electrons to iron for effective activation of nitrogen,prevent agglomeration of Fe nanoparticle (NPs) and restrain side reaction of carbon matrix to methane. | Pengqi Yan Wenhan Guo Zibin Liang Wei Meng Zhen Yin Siwei Li Mengzhu Li Mengtao Zhang Jie Yan Dequan Xiao Ruqiang Zou Ding Ma | 2019 | Nano Research2019，12，9： | 4 |
| 4 | Targeting β-secretase with RNAi in neural stem cells for Alzheimer's disease therapy显示文摘There are several major pathological changes in Alzheimer's disease,including apoptosis of cholinergic neurons,overactivity or overexpression of β-site amyloid precursor protein cleaving enzyme 1(BACE1) and inflammation.In this study,we synthesized a 19-nt oligonucleotide targeting BACE1,the key enzyme in amyloid beta protein(Aβ) production,and introduced it into the pSilenCircle vector to construct a short hairpin(shRNA) expression plasmid against the BACE1 gene.We transfected this vector into C17.2 neural stem cells and primary neural stem cells,resulting in downregulation of the BACE1 gene,which in turn induced a considerable reduction in reducing Aβ protein production.We anticipate that this technique combining cell transplantation and gene therapy will open up novel therapeutic avenues for Alzheimer's disease,particularly because it can be used to simultaneously target several pathogenetic changes in the disease. | Zhonghua Liu Shengliang Li Zibin Liang Yan Zhao Yulin Zhang Yaqi Yang Minjuan Wang Feng Li | 2013 | Neural Regeneration Research2013，8，33： | 4 |
| 5 | Metal-organic frameworks for electrochemical energy conversion:status and challenges显示文摘The quickly expanded energy consumption based on traditional fossil fuels has resulted in energy crises and severe environmental problems.Developing sustainable energy conversion technology is an important issue confronting the global energy security and consumption.Electrochemical energy storage and conversion is one of the most perspective renewable ways to produce carbon-free fuels via water splitting,and convert chemicals into electricity by fuel cells and metal-air batteries.A recent class of porous materials,metal-organic frameworks(MOFs),has been extensively explored as electrocatalysts or precursors to derive efficient composites in virtue of their large surface area,high porosity,tunable structures,and uniform dispersion of components[1].Because most MOFs are formed by inexpensive transition metals and commercial organic ligands. | Kexin Zhang Zibin Liang Ruqiang Zou | 2020 | Science China Chemistry2020，63，1： | 4 |
| 6 | Atomic Fe-N4 sites on electrospun hierarchical porous carbon nanofibers as an efficient electrocatalyst for oxygen reduction reaction显示文摘Porous carbon materials doped with atomically dispersed metal sites(ADMSs)are promising electrocatalysts for oxygen reduction reaction(ORR)electrocatalysis.In this work,we fabricated hierarchical porous nitrogen-doped carbon nanofibers with atomically dispersed Fe-N4 sites by carbonization of electrospinning iron-based metal-organic frameworks(MOFs)/polyacrylonitrile nanofibers for ORR electrocatalysis.Remarkably,the re sultant carbon nanofibers with atomically dispersed FeN4 sites exhibit extraordinary electrochemical performance with an onset potential of 0.994 V and a halfwave potential of 0.876 V in alkaline electrolyte,comparable to the benchmark commercial Pt/C catalyst.The high catalytic performance is originated from the unique hierarchically porous 1 D carbon structure and abundant highly active atomically dispersed Fe-N4 sites. | Ruiqin Zhong Chenxu Zhi Yingxiao Wu Zibin Liang Hassina Tabassum Hao Zhang Tianjie Qiu Song Gao Jinming Shi Ruqiang Zou | 2020 | Chinese Chemical Letters2020，31，6： | 1 |
| 7 | A new dual-ion battery based on amorphous carbon显示文摘The Na-based dual-ion batteries(NDIBs),combining the advantages of Na-ion batteries and dual-ion batteries,are attracting more attention due to their merits of abundant source,low cost and high energy density.However,the main challenges faced by NDIBs are their low capacity and poor cycling.Herein,we report a new ion storage mechanism for high-performance NDIBs using amorphous carbon(AOMC)as cathode.Unlike the graphite carbon that can only accommodate the PF6-anion(typical DIB system),the AOMC herein can both accommodate Na+cation and PF6-anion due to its amorphous feature,which is conceptually new dual-ion system for achieving much higher capacity.Ex-situ X-ray photoelectron spectroscopy,X-ray diffraction and Raman studies reveal that the disordered carbon in the AOMC can be transformed to the partial graphitic stacking in short range,improving both capacity and cycling stability of NDIBs.As a consequence,the AOMC delivers a highly reversible storage capacity of 136 mAhg-1 for 800 cycles at a very high current density of 2.0 Ag-1,much higher than all the reported NDIBs.Such concept can be generalized to develop high-performance dual-ion full cell using sodium ion preintercalated materials as anode and AOMC as cathode. | Wei(Alex)Wang Hanxin Huang Bin Wang Chang Qian Peihao Li Jinhui Zhou Zibin Liang Chao Yang Shaojun Guo | 2019 | Science Bulletin2019，64，21： | 1 |
| 8 | Distribution characteristics of photoinitiators and their flux estimation from the Pearl River Delta to the coastal waters of the South China Sea显示文摘Photoinitiators(PIs)are widely used in industrial polymerization processes.It has been reported that PIs are ubiquitous in indoor environments and that humans are exposed to PIs,but the occurrence of PIs in natural environments are rarely known.In the present study,25 PIs,including 9 benzophenones(BZPs),8 amine co-initiators(ACIs),4 thioxanthones(TXs)and 4 phosphine oxides(POs),were analyzed in water and sediment samples collected from eight riverine outlets of the Pearl River Delta(PRD).Eighteen,14,and 14 of the 25 target PIs were detected in water,suspended particulatematter(SPM)and sediment samples,respectively.The total concentrations of PIs in water,SPM,and sediment were in the ranges of 2.88–96.1 ng/L,9.25–923 ng/g dry weight(dw),and 3.79–56.9 ng/g dw,with geometric mean concentration(GM)of 10.8 ng/L,48.6 ng/g dw,and 17.1 ng/g dw,respectively.A significant linear regression was observed between the log partitioning coefficients(Kd)values of PIs and their log octanol water partition coefficient(Kow)values(R^(2)=0.535,p<0.05).The annual riverine input of PIs to the coastal waters of the South China Sea via eightmain outlets of the PRD was estimated to be 4.12×10^(3)kg/year,and the∑BZPs,∑ACIs,∑TXs and∑POs contributed to 1.96×10^(3),1.24×10^(3),89.6 and 830 kg/year,respectively.This is the first report of a systematic description of the occurrence characteristics of PIs exposure in water,SPM,and sediment.The environmental fate and risks of PIs in aquatic environments need further investigations. | Yuqing He Zibin Pan Xinxin Liang Ruiman Xie Yuying Sun Juan Li YaweiWang Lixi Zeng | 2023 | Journal of Environmental Sciences2023，，6： | 0 |
| 9 | Sarcopenia and sarcopenic obesity in patients awaiting liver transplantation显示文摘To the Editor,Sarcopenia includes the presence of both low skeletal muscle mass and low skeletal muscle function(strength and/or physical performance).A consensus definition of sarcopenia in cirrhosis patients is the phenotypic manifestation of the loss of muscle mass.1 On the basis of body composition analyses,sarcopenic obesity(SO)is defined as a combination of obesity and sarcopenia.2 Sarcopenia and SO have been detected associating with poor prognosis,including frailty,poor survival,infec-tion,and a greater length of hospital stay,physical impairment,and mortality. | Liang Fang Xuechun Liu Zibin Tian Yueping Jiang Xueli Ding Lingyun Zhang Xue Jing | 2023 | Portal Hypertension & Cirrhosis2023，2，3： | 0 |
| 10 | Probabilistic-Ellipsoid Hybrid Reliability Multi-Material Topology Optimization Method Based on Stress Constraint显示文摘This paper proposes a multi-material topology optimization method based on the hybrid reliability of the probability-ellipsoid model with stress constraint for the stochastic uncertainty and epistemic uncertainty of mechanical loads in optimization design.The probabilistic model is combined with the ellipsoidal model to describe the uncertainty of mechanical loads.The topology optimization formula is combined with the ordered solid isotropic material with penalization(ordered-SIMP)multi-material interpolation model.The stresses of all elements are integrated into a global stress measurement that approximates the maximum stress using the normalized p-norm function.Furthermore,the sequential optimization and reliability assessment(SORA)is applied to transform the original uncertainty optimization problem into an equivalent deterministic topology optimization(DTO)problem.Stochastic response surface and sparse grid technique are combined with SORA to get accurate information on the most probable failure point(MPP).In each cycle,the equivalent topology optimization formula is updated according to the MPP information obtained in the previous cycle.The adjoint variable method is used for deriving the sensitivity of the stress constraint and the moving asymptote method(MMA)is used to update design variables.Finally,the validity and feasibility of the method are verified by the numerical example of L-shape beam design,T-shape structure design,steering knuckle,and 3D T-shaped beam. | Zibin Mao Qinghai Zhao Liang Zhang | 2024 | Computer Modeling in Engineering & Sciences2024，140，7： | 0 |
| 11 | Novel STING-targeted PET radiotracer for alert and therapeutic evaluation of acute lung injury显示文摘Acute lung injury(ALI),as a common clinical emergency,is pulmonary edema and diffuse lung infiltration caused by inflammation.The lack of non-invasive alert strategy,resulting in failure to carry out preventive treatment,means high mortality and poor prognosis.Stimulator of interferon genes(STING)is a key molecular biomarker of innate immunity in response to inflammation,but there is still a lack of STING-targeted strategy.In this study,a novel STING-targeted PET tracer,[~(18)F]FBTA,was labeled with high radiochemical yield(79.7±4.3%)and molar activity(32.5±2.9 GBq/μmol).We confirmed that[~(18)F]FBTA has a strong STING binding affinity(K_d=26.86±6.79 nmol/L)and can be used for PET imaging in ALI mice to alert early lung inflammation and to assess the efficacy of drug therapy.Our STING-targeted strategy also reveals that[~(18)F]FBTA can trace ALI before reaching the computed tomography(CT)diagnostic criteria,and demonstrates its better specificity and distribution than[~(18)F]fluorodeoxyglucose([~(18)F]FDG). | Duo Xu Fan Yang Jiayao Chen Tianxing Zhu Fen Wang Yitai Xiao Zibin Liang Lei Bi Guolong Huang Zebo Jiang Hong Shan Dan Li | 2023 | Acta Pharmaceutica Sinica B2023，13，5： | 0 |
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