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| 1 | Microstructure and properties of as-cast Cu-Cr-Zr alloys with lanthanum addition显示文摘Cu-0.45 Cr-0.2 Zr-xLa(x = 0-0.48) alloys were prepared by vacuum casting. The effects of La addition and orientation on the microstructure and properties of the as-cast alloy were investigated by an optical microscope, a scanning electron microscope with an energy dispersive X-ray spectrometer, a tensile testing machine and an electrical conductivity tester. The result shows that the addition of La significantly refines the columnar grainsize and decreases the secondary dendrite arm spacing. Trace addition of La improves the room temperature ultimate tensile strength,elongation and electrical conductivity mainly by purifying during melting and casting. The ultimate tensile strength, elongation and electrical conductivity significantly decrease with the increase of La content due to formation of coarse particles and oxides, which severely harm the performance of the Cu-0.45 Cr-0.2 Zr-xLa alloys. The Cu-0.45 Cr-0.2 Zr-0.13 La alloy possesses a good combination of room temperature ultimate tensile strength, elongation and electrical conductivity. In addition, room temperature ultimate tensile strength and electrical conductivity along transverse direction of the ingot are higher than that along longitudinal direction,which is mainly ascribed to different distribution of grain boundary and grain orientation. | Jilin Li Lili Chang Shengli Li Xinde Zhu Zhongxin An | 2018 | Journal of Rare Earths2018，36，4： | 6 |
| 2 | MOF-derived Co-MOF,O-doped carbon as trifunctional electrocatalysts to enable highly efficient Zn-air batteries and water-splitting显示文摘Development of high-efficiency non-noble electrocatalysts for oxygen reduction reaction(ORR),oxygen evolution reaction(OER)and hydrogen evolution reaction(HER)is urgently needed for high-performance Zn-air batteries and overall water splitting.Here,a facile strategy to synthesize novel Co-MOF,O-doped carbon(Co-MOF-T)based on Zn,Co-doped glucosamine and ZIF-8 by pyrolysis at temperature T was demonstrated.The prepared Co-MOF-800 showed a superior oxygen reduction reaction(ORR)activity comparable to that of commercial Pt/C catalyst.In addition,this catalyst shows great potential in the overall water splitting due to the excellent oxygen evolution reaction(OER)and hydrogen evolution reaction(HER)activities.Based on the trifunctional activity,the primary Zn-air batteries using a Co-MOF-800 air electrode achieved a high open-circuit voltage of 1.38 V,a specific capacity of 671.6 mAh g^(-1) Zn,and a prominent peak power density of 144 mW cm^(-2).Also,the rechargeable Zn-air batteries based on CoMOF-800 air electrode could be smoothly run for 510 cycles with a low voltage gap of 0.58 V.Finally,the trifunctional Co-MOF-800 catalyst was applied to boost the electrochemical water splitting,demonstrating its promising potential as a green energy material for practical applications. | Xinde Duan Na Pan Can Sun Kexin Zhang Xukun Zhu Mingdao Zhang Li Song Hegen Zheng | 2021 | Journal of Energy Chemistry2021，30，5： | 5 |
| 3 | Synthesis, characterization and biological activity of the Schiff base derived from 3,4-dihydroxybenzaldehyde and thiosemicarbazid, and its complexes with nickel(II) and iron(II)显示文摘 | Xinde Zhu Chenggang Wang Zhiping Lu Yuanlin Dang | 1997 | Transition Metal Chemistry1997，，1： | 1 |
| 4 | Synthesis and biological activity of the Schiff base N,N'-bis (salicylidene) thiourea and its complexes of copper(II),nickel(II) and zinc(II)显示文摘 | Zhu Xinde Wang Chenggang Lu Zhiping | 1996 | Synth React Inorg Met Org Chem1996，26，6： | 1 |
| 5 | Synthesis and biological activity of the Schiff base N,N'- bis(salicylidene)thiourea and its complexes of copper (Ⅱ), nickel (Ⅱ) and zinc (Ⅱ) 显示文摘 | Zhu XInde Wang Chenggang Lu Zhiping | 1996 | Synth React Inorg Met - Org Chem1996，26，6： | 1 |
| 6 | Journal of Central China Normal University显示文摘 | Zhu Xinde Dong Yuanling | 1997 | 31(3):314-3161997，31，3： | 1 |
| 7 | Comparison of Time Interval Statistic and Pulse Shape Discrimination in Fast Neutron Detection Method with Liquid Scintillation Detector Loaded Gd显示文摘Neutron usually appears with gamma,which is requiring the detector has the capability of n gamma discrimination.Pulse shape discrimination(PSD)is a common approach of n,gamma judgment,but required a complex process to select a suitable discrimination factor,and poor performance in the low energy range.A method based on the time interval of adjacent Signals was disrupted and adopted to compare to pulse shape discrimination in the fast neutron detection method.A good agreement between the adopted method and PSD method was achieved,including the total count ratio and neutron count ratio.The comparison proves the correctness of the theoretical derivation and validates the method in practice.The advantages and limitations of the method based on time Interval of adjacent signals were analyzed.The method provides an effective way to confirm the calibration of the neutron detection of a liquid scintillation detector.Also,as a simple way only requiring the time information about events,the described method has large application potential in some case of fast neutron flux or intensity measurement. | Mohammed Adel Al-jumaili Qiang Du Jingjun Zhu Xinde Lin Wenbin Lin Changjian Tang Mustafa Raad Kadhim Haoyang Xing Shukui Liu | 2017 | 应用物理前沿(中英文版)2017，5，1： | 0 |
| 8 | Oxygen-contact charge transfer complexes in organic bicomponent systems显示文摘The O-2-CCT absorption spectra of bicomponent systems were measured. The influences of various organic compounds as well as the component concentration on the O-2-CCT formation ability were investigated. The results show that if the difference of O-2-CCT formation ability between the two components is rather large, such as the benzene/isopropyl ether system, only the O-2-CCT absorption of benzene appears, which arises from its higher O-2-CCT formation ability. If the difference of O-2-CCT formation ability is small, such as the isopropyl ether/ethanol system and the dioxane/isopropyl ether system, it is rather easy to form a dynamic equilibrium of two O-2-CCT between the two components, then only one absorption peak appears in the whole concentration range as a result of the repeated addition of the two kinds of O-2-CCT absorption. If the difference of O-2-CCT formation ability is in medium compared with the two cases above, such as the dioxane/ethanol system, there are two kinds of O-2-CCT absorption of dioxane and ethanol in the same system in the form of an equilibrium, then two absorption peaks can be detected in the middle concentration range as a result of the repeated addition of the two kinds of O-2-CCT absorption. | Junmin Zhu Zhengping Liu Weixiao Cao Xinde Feng | 1998 | Chinese Science Bulletin1998，43，21： | 0 |
| 9 | Alkaline hydrogen production promoted by small-molecule modification on flowerlike Co_(2)(OH)_(2)CO_(3)显示文摘Developing a low-cost and high-efficiency nonprecious metal-based catalyst for hydrogen evolution reaction(HER) is of great significance for the utilization of hydrogen energy.In this work,we report a molecular-modification strategy to fabricate a self-supported hydrogen evolution electrode,specially by grafting the macrocyclic molecules(HHTP=2,3,6,7,10,11-hexahydroxytriphenylene) on the surface of a cobaltous dihydroxy carbonate(COC) seed layer.The HHTP-COC electrode is endowed with a rodlike structure,which provides favorable access for charge transportation and mass exchange.The macrocyclic molecule structure in HHTP can be grafted on COC and improve the electrical conductivity,while the interaction between HHTP and COC induces the rearrangement of charge configuration on the surface.Due to the combination effects of several aspects,the HHTP-COC electrode achieves astonishing HER activity,with a low overpotential of 61.0 mV(η_(10),at the current density of 10 mA cm^(-2)) and excellent stability in alkaline condition.This kind of interface engineering based on the organic molecules can be applied to the design and manufacture of electrocatalysts in the field of energy conversion and storage. | Yue Liu Huan Zhang Chen Yang Ziyang Xu Yiyang Shi Xukun Zhu Xinde Duan Ling Qin Yachao Jin Li Song Mingdao Zhang Hegen Zheng | 2023 | Journal of Energy Chemistry2023，，9： | 0 |
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