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| 1 | Study on the evolution of ore-formation fluids for Au-Sb ore deposits and the mechanism of Au-Sb paragenesis and differentiation in the southwestern part of Guizhou Province, China显示文摘Ore deposits (occurrences) of Au, As, Sb, Hg, etc. distributed in Southwest Guizhou constitute the important portion of the low-temperature metallogenic domain covering a large area in Southwest China, with the Carlin-type Au and Sb deposits being the most typical ones. In this paper the Au and Sb ore deposits are taken as the objects of study. Through the petrographic analysis, microthermomitric measurement and Raman spectrophic analysis of fluid inclusions in gangue minerals and research on the S and C isotopic compositions in the gold ore deposits we can reveal the sources of ore-forming materials and ore-forming fluids and the rules of ore fluid evolution. Ore deposits of Au, Sb, etc. are regionally classified as the products of ore fluid evolution, and their ore-forming materials and ore fluids were probably derived mainly from the deep interior of the Earth. Fluid inclusion studies have shown that the temperatures of Au mineralization are within the range of 170-361℃,the salinities are 0.35 wt%-8 wt% NaCl eq.; the temperatures of Sb mineralization are 129.4-214℃ and the salinities are 0.18 wt%- 3.23 wt% NaCl eq.; the ore-forming fluid temperatures and salinities tend to decrease progressively. In the early stage (Au metallogenic stage) the ore-forming fluids contained large amounts of volatile components such as CO2, CH4, N2 and H2S, belonging to the H2O-CO2-NaCl fluid system; in the late stage (Sb metallogenic stage) the ore-forming fluids belong to the Sb-bearing H2O-NaCl system. The primitive ore-forming fluids may have experienced at least two processes of immiscibility: (1) when early ore-bearing hydrothermal solutions passed through rock strata of larger porosity or fault broken zones, CO2, CH4, N2 would escape from them, followed by the release of pressure, resulting in pressure release and boiling of primitive homogenous fluids, thereafter giving rise to their phase separation, thus leading to Au unloading and mineralization; and (2) in the late stage (Sb metallogenic stage ) a large volume of meteoric water was involved in the ore-forming fluids, leading to fluid boiling as a result of their encounter, followed by the drop of fluid temperature. As a result, the dissolubility of Sb decreased so greatly that Sb was enriched and precipitated as ores. Due to differences in physic-chemical conditions between Au and Sb precipitates, Au and Sb were respectively precipitated in different structural positions, thus creating such a phenomenon of Au/Sb paragenesis and differentiation in space. | WANG Zepeng XIA Yong SONG Xieyan LIU Jianzhong YANG Chengfu YAN Baowen | 2013 | Chinese Journal Of Geochemistry2013,32,1: | 10 |
| 2 | Geochemical characteristics and metallogenesis of Carlin-type gold deposits in the Sandu-Danzhai metallogenic zone,Guizhou Province,China显示文摘Geochemical studies of the Paiting and Miaolong Carlin-type gold deposits in the Sandu-Danzhai metal-logenic zone,Guizhou Province,have shown that the mineralized-altered rocks show LREE-enrichment patterns,generally displaying negative Eu anomalies(δEu=0.51?0.97) and unobvious negative Ce anomalies(δCe=0.86?0.99).Calcite and fluorite in relation with metallogenesis show MREE-enrichment patterns,generally displaying rather weak negative Eu anomalies(δEu=0.74?0.93) and weak negative Ce(δCe=0.70?0.98) anomalies.The δ13CPDB values of carbon in calcite are-1.61‰?-5.82‰,the δ18OSMOW values of oxygen are 13.97‰?19.24‰,and the δ34SCDT values of sulfur in stibnite are 17.72‰?21.68‰.In regard to δD and δ18O,ore-forming fluids pos-sess the characteristics of metamorphic water.The process of metallogenesis of the Carlin-type gold deposits is con-trolled by the Yanshanian tectonic activities.The Yanshanian movement promoted the migration and mobilization of metamorphic fluids in the extensively developed medium-to high-grade metamorphic rocks in this region,carrying primarily enriched gold and associated elements such as Hg,As,and Sb in the Sinian metamorphosed black shales and Lower Cambrian black shales.The ore-forming fluids found their way into a suitable metallogenic environment along the fault zone,followed by gold precipitation to form gold deposits. | YAN Baowen XIA Yong WANG Zepeng TAN Qingping WU Shourong FAN Erchuan | 2012 | Chinese Journal Of Geochemistry2012,31,3: | 4 |
| 3 | Sustainable functional urethral reconstruction:Maximizing early continence recovery in robotic-assisted radical prostatectomy显示文摘Objective:To evaluate the safety profile and short-term functional outcome of sustainable functional urethral reconstruction(SFUR)in robotic-assisted radical prostatectomy(RARP).Methods:One hundred and sixty-two consecutive prostate cancer patients who underwent RARP were retrospectively analyzed,in which 53 had undergone SFUR while the other 109 had undergone conventional RARP procedures.Immediate,2-week,1-month and 3-month continence recovery and other perioperative data were compared to evaluate short-term surgical and functional outcome.Results:The median age was 68 and 67 years in the experimental group and control group,respectively(pZ0.206),with a median prostate-specific antigen(PSA)of 13.6 ng/mL(interquartile range[IQR],8.46e27.32 ng/mL)in the experimental group and 13.84 ng/mL(IQR,9.12e26.80 ng/mL)in control group(pZ0.846).Immediate,2-week,1-month and 3-month continence recovery rates between the groups were 34.0%vs.3.7%,50.9%vs.14.7%,62.3%vs.27.5%,and 79.2%vs.63.3%(all p<0.05).The morphological changes made by the new reconstruction technique were maintained on magnetic resonance imaging(MRI)3 months postoperatively.Nerve-sparing procedures and adoption of the new reconstruction technique were significantly relevant to continence recovery on logistics regression model(p<0.001).Conclusions:SFUR is a safe and easy-to-handle modification that may contribute to early continence return for RARP.Long-term follow-up and prospective studies are required to further evaluate its value in postoperative quality-of-life improvement. | Zepeng Jia Yifan Chang Yan Wang Jing Li Min Qu Feng Zhu Huan Chen Bijun Lian Meimian Hua Yinghao Sun Xu Gao | 2021 | Asian Journal of Urology2021,8,1: | 2 |
| 4 | On cross-correlation indicators of an S-box显示文摘替换盒子(S 盒子) 经常在许多对称的加密算法被用作最重要的非线性的部件。S 盒子的密码的性质直接影响整个零系统的安全。最近,概括了全球雪崩特征(GGAC ) 被介绍测量在二任意的布尔功能之间的关联。在这份报纸,更好评估 S 盒子的安全,我们在场为它的二跨关联的指示物。另外,由学习相关性质在二平衡布尔功能之间跨关联,我们为 S 盒子为二平衡功能并且也在与 GGAC 有关的 sum-of-squares 指示物上建议更低的界限。 | Sheng GAO Wenping MA Zepeng ZHUO Fenghe WANG | 2011 | Frontiers of Computer Science2011,5,4: | 2 |
| 5 | Geological and geochemical characteristics of the Baogudi Carlintype gold district(Southwest Guizhou, China) and their geological implications显示文摘The newly discovered Baogudi gold district is located in the southwestern Guizhou Province,China,where there are numerous Carlin-type gold deposits.To better understand the geological and geochemical characteristics of the Baogudi gold district,we carried out petrographic observations,elemental analyses,and fluid inclusion and isotopic composition studies.We also compared the results with those of typical Carlin-type gold deposits in southwestern Guizhou.Three mineralization stages,namely,the sedimentation diagenesis,hydrothermal(main-ore and late-ore substages),and supergene stages,were identified based on field and petrographic observations.The main-ore and late-ore stages correspond to Au and Sb mineralization,respectively,which are similar to typical Carlin-type mineralization.The mass transfer associated with alteration and mineralization shows that a significant amount of Au,As,Sb,Hg,Tl,Mo,and S were added to mineralized rocks during the main-ore stage.Remarkably,arsenic,Sb,and S were added to the mineralized rocks during the late-ore stage.Element migration indicates that the sulfidation process was responsible for ore formation.Four types of fluid inclusions were identified in ore-related quartz and fluorite.The main-ore stage fluids are characterized by an H2O–NaCl–CO2–CH4±N2system,with medium to low temperatures(180–260℃)and low salinity(0–9.08%NaCl equivalent).The late-ore stage fluids featured H2O–NaCl±CO2±CH4,with low temperature(120–200℃)and low salinity(0–7.48%Na Cl equivalent).The temperature,salinity,and CO2and CH4concentrations of ore-forming fluids decreased from the main-ore stage to the late-ore stage.The calculated δ^13C,d D,and δ^18O values of the ore-forming fluids range from-14.3 to-7.0%,-76 to-55.7%,and 4.5–15.0%,respectively.Late-ore-stage stibnite had δ^34S values ranging from-0.6 to 1.9%.These stable isotopic compositions indicate that the ore-forming fluids originated mainly from deep magmatic hydrothermal fluids,with minor contributions from strata.Collectively,the Baogudi metallogenic district has geological and geochemical characteristics that are typical of Carlin-type gold deposits in southwest Guizhou.It is likely that the Baogudi gold district,together with other Carlin-type gold deposits in southwestern Guizhou,was formed in response to a single widespread metallogenic event. | Songtao Li Yong Xia Jianzhong Liu Zhuojun Xie Qinping Tan Yimeng Zhao Minghua Meng Lijin Tan Rong Nie Zepeng Wang Guanghong Zhou Haiyan Guo | 2019 | Acta Geochimica2019,38,4: | 1 |
| 6 | Constructions of Balanced Quaternary Sequences显示文摘Binary and quaternary sequences have received a lot of attention since they are easy to be implemented as multiple-access sequence in practical communication systems,radar,and cryptography.In this paper,the two complete binary sequence of period N are analyzed.For odd prime N,new balanced quaternaruy sequences of even period 2 N are constructed using Gary mapping.Furthermore,we computer the complete autocorrelation distributions of this sequence. | WANG Jingjing ZHAO Min YANG Zhiyao GUO Yuyan ZHUO Zepeng | 2020 | Chinese Journal of Electronics2020,29,3: | 1 |
| 7 | Analytical method of the rolling resistance of radial tire base on ANSYS显示文摘 | Wang Zepeng Ke Jiana Ma Lianxiang | 2012 | Key Engineering Materials2012,501,: | 1 |
| 8 | Constructing heterostructures of ZIF-67 derived C,N doped Co_(2)P and Ti_(2)VC_(2)T_(x)MXene for enhanced OER显示文摘Oxygen evolution reaction(OER)is central to technologies such as electrochemical water splitting,and developing efficient and low-cost non-precious metal electrocatalysts for OER is of great significance to reducing cell voltage and developing hydrogen production by electrochemical water splitting.Herein,we prepared a carbon,nitrogen co-doped porous Co_(2)P derived from the metal-organic framework(ZIF-67),which is anchored on bimetallic MXene nanosheets(named MX@MOF-Co_(2)P).It was used as the OER catalyst and exhibited great electrocatalytic performance with very small overpotentials(246 mV at 10 mA^(-2)and 407 mV at 200 mA cm^(-2))as well as ultralow Tafel slope(28.18 mV dec^(-1)).Combining charac-terizations and theoretical calculations,it was found that the remarkable performance was from follows:the obtained MX@MOF-Co_(2)P inherited the porous structure of the pristine MOF with a large number of open active sites;carbon and nitrogen doping also modulated the electronic structure of the active center;the synergistic effect between cobalt phosphide and MXenes booted the electronic transfer.This work represents a promising strategy for the development of non-precious metal catalysts derived from metal-organic frameworks to achieve efficient energy conversion. | Jinzhou Li Chao Chen Zepeng Lv Wansen Ma Meng Wang Qian Li Jie Dang | 2023 | Journal of Materials Science & Technology2023,,14: | 1 |
| 9 | Dependence of chargeaccumulation on sample thickness in Nano-Si02 doped LDPE显示文摘 | LV Zepeng WANG Xia WU Kai | 2013 | IEEE Transactions on Dielectrics and Electrical Insulation2013,20,1: | 1 |
| 10 | Surface-state triggered solvatochromism of carbonized polymer dot and its two-photon luminescence显示文摘This study reports a new nitrogen-doped carbonized polymer dot(CPD)-based solvatochromic probe.Its color-changing for different solvents was explored in detail by the measurements of photophysical parameters(involving Stokes shifts,fluorescence quantum yield,fluorescence lifetime,radiative decay rate constant,and non-radiative decay rate constant)and the following analyses according to Lippert–Mataga equation and Kamlet–Taft model.The hydrogen bonding effect of the CPD in protonic solvents was semi-quantitatively assessed.It takes charge of the solvatochromic phenomenon,especially in proton solvents.Interestingly,this CPD exhibits two-photon solvatochromism.Moreover,the relations between the photophysical parameters and the surface states of CPD in aprotic and proton solvents were depicted.The results reveal the nitrogen doping in the CPD impacts the up-and down-conversion solvatochromic features from the comparison between N-free and N-doped CPDs in many characterizations.In addition,this N-doped CPD was dispersed into polymer matrices to fabricate tunable solid-state luminescent films,which is another model for evidencing the interactions of the CPD with surroundings.This study is of significance in understanding the surface-state controlled luminescence in the CPDs,and will be beneficial for developing new smart,responsive carbon-based nanoprobes. | Zepeng Huo Weiqing Xu Gang Chen Zizhun Wang Shuping Xu | 2022 | Nano Research2022,15,3: | 1 |
| 11 | Kinetic Limits of Graphite Anode for Fast‑Charging Lithium‑Ion Batteries显示文摘Fast-charging lithium-ion batteries are highly required,especially in reducing the mileage anxiety of the widespread electric vehicles.One of the biggest bottlenecks lies in the sluggish kinetics of the Li^(+)intercalation into the graphite anode;slow intercalation will lead to lithium metal plating,severe side reactions,and safety concerns.The premise to solve these problems is to fully understand the reaction pathways and rate-determining steps of graphite during fast Li^(+)intercalation.Herein,we compare the Li^(+)diffusion through the graphite particle,interface,and electrode,uncover the structure of the lithiated graphite at high current densities,and correlate them with the reaction kinetics and electrochemical performances.It is found that the rate-determining steps are highly dependent on the particle size,interphase property,and electrode configuration.Insufficient Li^(+)diffusion leads to high polarization,incomplete intercalation,and the coexistence of several staging structures.Interfacial Li^(+)diffusion and electrode transportation are the main rate-determining steps if the particle size is less than 10μm.The former is highly dependent on the electrolyte chemistry and can be enhanced by constructing a fluorinated interphase.Our findings enrich the understanding of the graphite structural evolution during rapid Li^(+)intercalation,decipher the bottleneck for the sluggish reaction kinetics,and provide strategic guidelines to boost the fast-charging performance of graphite anode. | Suting Weng Gaojing Yang Simeng Zhang Xiaozhi Liu Xiao Zhang Zepeng Liu Mengyan Cao Mehmet Nurullah Ateş Yejing Li Liquan Chen Zhaoxiang Wang Xuefeng Wang | 2023 | Nano-Micro Letters2023,15,11: | 1 |
| 12 | Localized-domains staging structure and evolution in lithiated graphite显示文摘Intercalation provides to the host materials a means for controlled variation of many physical/chemical properties and dominates the reactions in metal‐ion batteries.Of particular interest is the graphite intercalation compounds with intriguing staging structures,which however are still unclear,especially in their nanostructure and dynamic transition mechanism.Herein,the nature of the staging structure and evolution of the lithium(Li)‐intercalated graphite was revealed by cryogenic‐transmission electron microscopy and other methods at the nanoscale.The intercalated Li‐ions distribute unevenly,generating local stress and dislocations in the graphitic structure.Each staging compound is found macroscopically ordered but microscopically inhomogeneous,exhibiting a localized‐domains structural model.Our findings uncover the correlation between the long‐range ordered structure and short‐range domains,refresh the insights on the staging structure and transition of Li‐intercalated/deintercalated graphite,and provide effective ways to enhance the reaction kinetic in rechargeable batteries by defect engineering. | Suting Weng Siyuan Wu Zepeng Liu Gaojing Yang Xiaozhi Liu Xiao Zhang Chu Zhang Qiuyan Liu Yao Huang Yejing Li Mehmet NAteş Dong Su Lin Gu Hong Li Liquan Chen Ruijuan Xiao Zhaoxiang Wang Xuefeng Wang | 2023 | Carbon Energy2023,5,1: | 1 |
| 13 | Mechanism of space charge formation in cross linked polyethylene (XLPE) under temperature gradient显示文摘 | LYU Zepeng CAO Junzheng WANG Xia | 2015 | IEEE Transactions on Di- electrics and Electrical Insulation2015,22,6: | 1 |
| 14 | Effect of microbial fermentation on the sensory characteristics and chemical compositions of Chinese sweet tea(Lithocarpus litseifolius(Hance)Chun)显示文摘Sweet tea,which has hundreds of years of use among in Chinese folk,is a traditional herbal tea with pleasant sweetness,bitterness and astringency.In the current study,we used traditional microbial fermentation to improve sensory characteristics of sweet tea,especially for the reduction of bitterness and astringency.The dynamic changes of non-volatile,volatile compounds and microbial community were investigated during microbial fermentation.The contents of polyphenols,flavonoids,soluble sugar,soluble protein,catechins and dihydrochalcones decreased significantly while the tea pigments,free amino acids and gallic acid content inversely increased during microbial fermentation.A total of 61 volatile compounds were identified and quantified in sweet tea,of which 20 key compounds were identified as odor active compounds(OAV),including 3 aldehydes,1 ketone,4 alcohols,9 esters,4 alkenes and 3 other compounds.In addition,eight fungi and four bacteria were considered as core microorganisms,such as Aspergillus,Alternaria,Cladosporium,Epicoccum,Itersonilia,Penicillium,Periconia,Wallemia,Aureimonas,Enterobacter,Klebsiella and Stenotrophomonas,which were significantly correlated with non-volatile compounds and flavor compounds.These results provided theoretical guidance for processing of fermented sweet tea. | Weimin Huang Changyi Zhang Zepeng Gu Cheng Li Zhengfeng Fang Zhen Zeng Zhiqing Zhang Bin Hu Hong Chen Wenjuan Wu Tiqiang Wang Xiguo Lan Yuntao Liu | 2022 | Food Bioscience2022,46,2: | 1 |
| 15 | Assessment of Lubrication Property and Machining Performance of Nanofluid Composite Electrostatic Spraying(NCES)Using Different Types of Vegetable Oils as Base Fluids of External Fluid显示文摘The current study of minimum quantity lubrication(MQL)concentrates on its performance improvement.By contrast with nanofluid MQL and electrostatic atomization(EA),the proposed nanofluid composite electrostatic spraying(NCES)can enhance the performance of MQL more comprehensively.However,it is largely influenced by the base fluid of external fluid.In this paper,the lubrication property and machining performance of NCES with different types of vegetable oils(castor,palm,soybean,rapeseed,and LB2000 oil)as the base fluids of external fluid were compared and evaluated by friction and milling tests under different flow ratios of external and internal fluids.The spraying current and electrowetting angle were tested to analyze the influence of vegetable oil type as the base fluid of external fluid on NCES performances.The friction test results show that relative to NCES with other vegetable oils as the base fluids of external fluid,NCES with LB2000 as the base fluid of external fluid reduced the friction coefficient and wear loss by 9.4%-27.7%and 7.6%-26.5%,respectively.The milling test results display that the milling force and milling temperature for NCES with LB2000 as the base fluid of external fluid were 1.4%-13.2%and 3.6%-11.2%lower than those for NCES with other vegetable oils as the base fluids of external fluid,respectively.When LB2000/multi-walled carbon nanotube(MWCNT)water-based nanofluid was used as the external/internal fluid and the flow ratio of external and internal fluids was 2:1,NCES showed the best milling performance.This study provides theoretical and technical support for the selection of the base fluid of NCES external fluid. | Yu Su Zepeng Chu Le Gong Bin Wang Zhiqiang Liu | 2023 | Chinese Journal of Mechanical Engineering2023,36,4: | 0 |
| 16 | A genetically engineered Escherichia coli that senses and degrades tetracycline antibiotic residue显示文摘Due to the abuse of antibiotics,antibiotic residues can be detected in both natural environment and various industrial products,posing threat to the environment and human health.Here we describe the design and implementation of an engineered Escherichia coli capable of degrading tetracycline(Tc)-one of the commonly used antibiotics once on humans and now on poultry,cattle and fisheries.A Tcdegrading enzyme,TetX,from the obligate anaerobe Bacteroides fragilis was cloned and recombinantly expressed in E.coli and fully characterized,including its Km and kcat value.We quantitatively evaluated its activity both in vitro and in vivo by UVeVis spectrometer and LC-MS.Moreover,we used a tetracycline inducible amplification circuit including T7 RNA polymerase and its specific promoter PT7 to enhance the expression level of TetX,and studied the dose-response of TetX under different inducer concentrations.Since the deployment of genetically modified organisms(GMOs)outside laboratory brings about safety concerns,it is necessary to explore the possibility of integrating a kill-switch.Toxin-Antitoxin(TA)systems were used to construct a mutually dependent host-plasmid platform and biocontainment systems in various academic and industrious situations.We selected nine TA systems from various bacteria strains and measured the toxicity of toxins(T)and the detoxifying activity of cognate antitoxins(A)to validate their potential to be used to build a kill-switch.These results prove the possibility of using engineered microorganisms to tackle antibiotic residues in environment efficiently and safely. | Zepeng Mu Zhuoning Zou Ye Yang Wenbo Wang Yue Xu Jianyi Huang Ruiling Cai Ye Liu Yajin Mo Boyi Wang Yiqun Dang Yongming Li Yushan Liu Yueren Jiang Qingyang Tan Xiaohong Liu Cheng Hu Hua Li Sha Wei Chunbo Lou Yang Yu Jiangyun Wang | 2018 | Synthetic and Systems Biotechnology2018,3,3: | 0 |
| 17 | Texturing and evaluation of concrete pavement surface:A state-of-the-art review显示文摘Concrete pavement is accompanied by two major functional properties,namely noise emission and friction,which are closely related to pavement surface texture.While several technologies have been developed to mitigate tirepavement noise and improve driving friction by surface texturization,limited information is available to compare the advantages and disadvantages of different surface textures.In this study,a state-of-the-art and state-of-thepractice review is conducted to investigate the noise reduction and friction improvement technologies for concrete pavement surfaces.The commonly used tests for characterizing the surface texture,skid resistance,and noise emission of concrete pavement were first summarized.Then,the texturing methods for both fresh and hardened concrete pavement surfaces were discussed,and the friction,noise emission and durability performances of various surface textures were compared.It is found that the next generation concrete surface(NGCS)texture generally provides the best noise emission performance and excellent friction properties.The exposed aggregate concrete(EAC)and optimized diamond grinding textures are also promising alternatives.Lastly,the technical parameters for the application of both diamond grinding and diamond grinding&grooving textures were recommended based on the authors'research and practical experience in Germany and the US.This study offers a convenient reference to the pavement researchers and engineers who seek to quickly understand relevant knowledge and choose the most appropriate surface textures for concrete pavements. | Zhen Leng Zepeng Fan Pengfei Liu Jonas Kollmann Markus Oeser Dawei Wang Xi Jiang | 2023 | Journal of Road Engineering2023,3,3: | 0 |
| 18 | The Walsh Transform of a Class of Boolean Functions显示文摘The Walsh transform is an important tool to investigate cryptographic properties of Boolean functions.This paper is devoted to study the Walsh transform of a class of Boolean functions defined as g(x)=f(x)Tr^(n)_(1)(x)+h(x)Tr^(n)_(1)(δx),by making use of the known conclusions of Walsh transform and the properties of trace function,and the conclusion is obtained by generalizing an existing result. | JIANG Niu ZHUO Zepeng CHEN Guolong WANG Liting | 2021 | Wuhan University Journal of Natural Sciences2021,26,6: | 0 |
| 19 | Planar Serial Manipulator Motion Synthesis显示文摘This paper deals with the universal serial manipulator on the inverse kinematics problem of plane type,the fast working space solution method,and the obstacle avoidance path planning method. With the vector projection as the main constraint condition of the target,it proposes a general form of the inverse kinematics solution which does not depend on the robot configuration of freedom degree. By identifying the target vector direction maximum and minimum workspace boundary and determining the destination vector by thick search on the workspace boundary method,an expressing method of the polar coordinate form of work space is then introduced. Finally,according to the form of plane trajectory planning for obstacle avoidance problem,the method of solving the inverse kinematics solution of the concave and convex forms of the safe obstacle avoidance area is improved. The simulation results verify that the proposed method has feasibility and generality. | Yanhui Wei Han Han Zepeng Wang Xin Liu Guangchun Li | 2015 | Journal of Harbin Institute of Technology(New Series)2015,22,2: | 0 |
| 20 | Dynamics of an impurity ion transport in oil-paper insulation under various electric fields显示文摘The ionic transport process is an important counterpart to charge transport in oil-paper insulation,and it significantly impacts oil flow electrification at the oil-paper interface.Despite this,the dynamics of this phenomenon and the underlying mechanisms remain unclear,particularly at the molecular level.To understand this fundamental aspect,we conduct Molecular Dynamics study on the transport behaviour of an impurity ion in different oil-paper insulation models under various external electric fields.Different influence factors,such as external electric fields,temperatures,and local structural characteristics,are investigated in relation to the corresponding ionic mobility in different polymer models.According to the simulations,ionic mobility and its response to electric fields are higher in weaker electrostatic models.As a result,mineral oil exhibits the highest ionic mobility and the most substantial enhancement of ionic mobility by external electric fields,followed by vegetable oil,oil-paper blends,and insulating paper.This significant deviation in ionic mobility between oil and paper leads to the formation of an electric double layer near the oil-paper interface.The underlying physical mechanisms of different ionic mobility and its response to the electric field in different polymer models could be explained by the different polymer structural influences in terms of interaction energy and coordination numbers in a static manner,as well as by the interactions between the impurity ion and its surrounding atoms in terms of lifetime correlation functions and velocity autocorrelation functions in a dynamic manner.In addition,the influence of temperature on ionic mobility in mineral and vegetable oil is examined,and their activation energies are calculated.Advancing in the fundamental understanding of the dynamics of the ion transport process in oil-paper insulation is vital to improving their insulating properties for oil-impregnated power transformers. | Yuanyang Ren Yang Wang Qiankai Zhang Jiayu Xiong Wen Cao Zepeng Lv Kai Wu | 2024 | High Voltage2024,9,1: | 0 |