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| 1 | Cosmogenic ^(10)Be dating of Guxiang and Baiyu Glaciations显示文摘Guxiang and Baiyu Glaciations are two previously recognized local glaciations of the Tibetan Plateau. They have been widely used as the reference standard for classifying Late Quaternary glaciations on the Tibetan Plateau and its surrounding mountains. However, the numerical chronologies of both glaciations have been lacking. In this study, cosmogenic 10Be dating was undertaken to define the timing of these two glaciations. The surface boulders deposited by the glaciers of the Guxiang and Baiyu Glaciations have exposure ages of 112.9±16.7―136.5±15.8 ka BP and 11.1±1.9―18.5±2.2 ka BP, respectively. It is likely that the Guxiang and Baiyu Glaciations correspond to marine isotope stages 6 and 2, respectively. | ZHOU ShangZhe XU LiuBing PATRICK M. Colgan DAVID M. Mickelson WANG XiaoLi WANG Jie ZHONG Wei | 2007 | Chinese Science Bulletin2007，52，10： | 28 |
| 2 | Novel Insights into Energy Storage Mechanism of Aqueous Rechargeable Zn/MnO2 Batteries with Participation of Mn2+显示文摘Aqueous rechargeable Zn/MnO2 zinc-ion batteries(ZIBs)are reviving recently due to their low cost,non-toxicity,and natural abundance.However,their energy storage mechanism remains controversial due to their complicated electrochemical reactions.Meanwhile,to achieve satisfactory cyclic stability and rate performance of the Zn/MnO2 ZIBs,Mn2+ is introduced in the electrolyte(e.g.,ZnSO4 solution),which leads to more complicated reactions inside the ZIBs systems.Herein,based on comprehensive analysis methods including electrochemical analysis and Pourbaix diagram,we provide novel insights into the energy storage mechanism of Zn/MnO2 batteries in the presence of Mn2+.A complex series of electrochemical reactions with the coparticipation of Zn2+,H+,Mn2+,SO42-,and OH-were revealed.During the first discharge process,co-insertion of Zn2+ and H+ promotes the transformation of MnO2 into ZnxMnO4,MnOOH,and Mn2O3,accompanying with increased electrolyte pH and the formation of ZnSO4·3 Zn(OH)2-5 H2O.During the subsequent charge process,ZnxMnO4,MnOOH,and Mn2O3 revert to a-MnO2 with the extraction of Zn2+ and H+,while ZnSO4·3Zn(OH)2·5H2O reacts with Mn2+ to form ZnMn3O7·3 H2O.In the following charge/discharge processes,besides aforementioned electrochemical reactions,Zn2+ reversibly insert into/extract from α-MnO2,ZnxMnO4,and ZnMn3O7·3H2O hosts;ZnSO4·3Zn(OH)2·5 H2O,Zn2Mn3O8,and ZnMn2O4 convert mutually with the participation of Mn2+.This work is believed to provide theoretical guidance for further research on high-performance ZIBs. | Yongfeng Huang Jian Mou Wenbao Liu Xianli Wang Liubing Dong Feiyu Kang Chengjun Xu | 2019 | Nano-Micro Letters2019，11，3： | 11 |
| 3 | High-Performance Aqueous Zinc-Ion Batteries Realized by MOF Materials显示文摘Rechargeable aqueous zinc-ion batteries(ZIB s) have been gaining increasing interest for large-scale energy storage applications due to their high safety,good rate capability,and low cost.However,the further development of ZIB s is impeded by two main challenges:Currently reported cathode materials usually suffer from rapid capacity fading or high toxicity,and meanwhile,unstable zinc stripping/plating on Zn anode seriously shortens the cycling life of ZIBs.In this paper,metal-organic framework(MOF) materials are proposed to simultaneously address these issues and realize high-performance ZIB s with Mn(BTC) MOF cathodes and ZIF-8-coated Zn(ZIF-8@Zn) anodes.Various MOF materials were synthesized,and Mn(BTC) MOF was found to exhibit the best Zn^2+-storage ability with a capacity of 112 mAh g^-1.Zn^2+ storage mechanism of the Mn(BTC) was carefully studied.Besides,ZIF-8@Zn anodes were prepared by coating ZIF-8 MOF material on Zn foils.Unique porous structure of the ZIF-8 coating guided uniform Zn stripping/plating on the surface of Zn anodes.As a result,the ZIF-8@Zn anodes exhibited stable Zn stripping/plating behaviors,with 8 times longer cycle life than bare Zn foils.Based on the above,high-performance aqueous ZIBs were constructed using the Mn(BTC) cathodes and the ZIF-8@Zn anodes,which displayed an excellent long-cycling stability without obvious capacity fading after 900 charge/discharge cycles.This work provides a new opportunity for high-performance energy storage system. | Xuechao Pu Baozheng Jiang Xianli Wang Wenbao Liu Liubing Dong Feiyu Kang Chengjun Xu | 2020 | Nano-Micro Letters2020，12，11： | 5 |
| 4 | Towards High-Energy and Anti-Self-Discharge Zn-Ion Hybrid Supercapacitors with New Understanding of the Electrochemistry显示文摘Aqueous Zn-ion hybrid supercapacitors(ZHSs)are increasingly being studied as a novel electrochemical energy storage system with prominent electrochemical performance,high safety and low cost.Herein,high-energy and anti-self-discharge ZHSs are realized based on the fibrous carbon cathodes with hierarchically porous surface and O/N heteroatom functional groups.Hierarchically porous surface of the fabricated free-standing fibrous carbon cathodes not only provides abundant active sites for divalent ion storage,but also optimizes ion transport kinetics.Consequently,the cathodes show a high gravimetric capacity of 156 mAh g^(−1),superior rate capability(79 mAh g^(−1)with a very short charge/discharge time of 14 s)and exceptional cycling stability.Meanwhile,hierarchical pore structure and suitable surface functional groups of the cathodes endow ZHSs with a high energy density of 127 Wh kg−1,a high power density of 15.3 kW kg^(−1)and good anti-self-discharge performance.Mechanism investigation reveals that ZHS electrochemistry involves cation adsorption/desorption and Zn_(4)SO_(4)(OH)_(6)·5H_(2)O formation/dissolution at low voltage and anion adsorption/desorption at high voltage on carbon cathodes.The roles of these reactions in energy storage of ZHSs are elucidated.This work not only paves a way for high-performance cathode materials of ZHSs,but also provides a deeper understanding of ZHS electrochemistry. | Yang Li Wang Yang Wu Yang Ziqi Wang Jianhua Rong Guoxiu Wang Chengjun Xu Feiyu Kang Liubing Dong | 2021 | Nano-Micro Letters2021，13，6： | 2 |
| 5 | The sedimentary source, planform stability and shore normal morphological change of the Xichong beach on the southern coast of the Dapeng Peninsula of Shenzhen, Guangdong Province, China显示文摘The coast of the Dapeng Peninsula has been honored as one of 'the eight most beautiful coasts in China'. The most precious tourism resource for the peninsula is headland bay beaches, among which the beach at Xichong on the southern coast of the peninsula is the longest and the most important one. The information of the stability, sedimentary source and shape change of the beach is very important for maintaining the beach in terms of sustainable development of the peninsula. Heavy minerals in the sand of the beach and the inland stream at Xichong are compared with those of a nearby beach on the same coast to determine the beach sand source; with help of a computer software, MEPBAY, the equilibrium planforms of the beaches on the peninsula are compared with those of an island without rivers to evaluate the stream's effects on the beach stability; cross shore profiles along the Xichong beach are also surveyed in different seasons of a year to assess the annual shore normal beach changes affected by the stream input, and the relation between the equilibrium planform state and cross shore changes of the beach. It is shown that(1) stream is the main sedimentary source of the beach and the weathering materials of the rocky headlands on both sides of the bay transported by waves are the second source for the beach but it is limited, sand from an inner shelf is not the sedimentary source for the beach at present and was not even during the Holocene transgression;(2) the Xichong beach cannot reach static equilibrium around the entire bay shoreline, the segment of the shoreline where a stream outlet is located is in dynamic equilibrium, and the unstable section occurs in the wave shadow region in the lee of an offshore island;(3) no matter whether the section of the beach shoreline at Xichong is in an equilibrium state or not, it is eroded in the typhoon season and recovered after the season, the maximum change in erosion and accretion occurs in the unstable segment;(4) the Xichong beach can only have small sand body since it is supplied with sand mainly form inland streams, resulting in a possible danger in which sand loss induced by human activities or huge storms cannot be replenished naturally. | ZHANG Song WANG Wei HUANG Rihui XU Liubing | 2015 | Acta Oceanologica Sinica2015，34，3： | 2 |
| 6 | Quaternary glaciations recorded by glacial and fluvial landforms in the Shaluli Mountains, southeastern Tibetan Plateau 显示文摘 | Xu Liubing Zhou Shangzhe | 2009 | Geomorphology2009，103，： | 1 |
| 7 | Few-layer Ti3C2Tx MXene delaminated via flash freezing for high-rate electrochemical capacitive energy storage显示文摘Few-layer Ti3C2Tx MXene is synthesized from multi-layered Ti3C2Tx via a flash freezing-assisted delamination process.During the flash freezing process,the water molecules in the interlayers of multi-layered MXene are induced to rearrange and produce volume expansion,thus notably expand the MXenes’interlayer distance to form few-layer MXene.The synthesized few-layer Ti3C2Tx MXene nanosheets display a very small thickness(less than 5 Ti3C2 atom-layers)and expanded interlayer spacing.Consequently,the few-layer Ti3C2Tx exhibits enhanced capacitance(255 F g^-1 vs.177 F g^-1 for the multi-layered Ti3C2Tx)and significantly optimized rate capability(150 F g^-1 at 200 mV s^-1 vs.25 F g^-1 for the multi-layered Ti3C2Tx),because redox-active sites in the few-layer MXene are easily accessible to electrolyte ions.Moreover,an asymmetric supercapacitor is constructed using the few-layer Ti3C2Tx negative electrode and an activated carbon fiber positive electrode.The asymmetric supercapacitor presents a high energy density of 17.9 Wh kg^-1 and a high power density of 14 kW kg^-1,which is inseparable from its wide voltage window of 1.4 V and the good rate performance of the few-layer Ti3C2Tx MXene electrode.Overall,the flash freezing-assist delamination provides an effective and environmental-friendly strategy to synthesize few-layer MXene materials for high-rate electrochemical energy storage. | Xianli Wang Liubing Dong Wenbao Liu Yongfeng Huang Xuechao Pu Jinjie Wang Feiyu Kang Jia Lia Chengjun Xu | 2020 | Journal of Energy Chemistry2020，29，9： | 1 |
| 8 | Fatigue behaviors of Z2CND18.12N stainless steel under thermal-mechanical cycling显示文摘Tests under mechanical strain control were performed to investigate the TMF behavior of Z2CND18.12N within the temperature range between 150–550 ? C. Different strain amplitudes and phase-angles were applied. Total strain controlled low cycle fatigue test was also performed at the peak temperature of TMF cycling. The results show that the cyclic stress response of the material displayed an initial hardening regime followed by a saturation period and then cyclic softening till failure. The TMF cycling leads to the development of significant amounts of mean stress. Some life prediction models were employed to predict the TMF life of Z2CND18.12N, and the results indicate that the energy-based models provide good prediction on the thermal-mechanical fatigue behaviors of this material. An optical microscopic observation shows that the surface crack initiations and crack propagations are typically transgranular mode. | Liubing WANG Dunji YU Fei XUE Weiwei YU Jian CHEN Xu CHEN | 2011 | Acta Metallurgica Sinica(English Letters)2011，24，2： | 1 |
| 9 | Potential of quartz OSL dating on moraine deposits from eastern Tibetan Plat- eau using SAR protocol显示文摘 | Ou Xianjiao Xu Liubing Lai Zhongping | 2010 | Quaternary Geochronology2010，5，2： | 1 |
| 10 | Evidence for glaciation predating MIS-6 in the eastern Nyainqêntanglha Range, southeastern Tibet显示文摘Southeastern Tibet is one of the most glaciated regions on the Tibetan Plateau both at present and during the Quaternary. Numerical dating of glacial deposits has allowed the establishment of a provisional chronology of Quaternary glacial fluctuations in this region, with the oldest glaciation(Guxiang Glaciation) occurring in marine oxygen isotope stage 6(MIS-6).During our recent field investigations, a morphostratigraphically older lateral moraine than that of the Guxiang Glaciation has been first identified, which is ~500–600 m above the Guxiang Glaciation moraine and discontinuously preserved on valley shoulders in the Bodui Zangbo River valley, eastern Nyainqêntanglha Range in southeastern Tibet. Considering the moraine is best preserved at Nitong Village, here we name the glacier advance which deposited the moraine as 'Nitong Glaciation'. Using electron spin resonance(ESR) technique, we dated the Nitong Glaciation moraine to 506.3±60.4 ka. Taking into account the age error and climatic conditions, we consider it most likely that the Nitong Glaciation occurred during MIS-12, although it might had happened sometime earlier. | Shangzhe ZHOU Jinming XIE Xianjiao OU Liubing XU Yong SUN Xuezhen ZENG Xiaoxia WEN Renrong CHEN Hong YANG Xianmei HUANG Yazhong ZHOU Jinjin SUN | 2021 | Science China Earth Sciences2021，64，4： | 0 |
| 11 | Roadmap for rechargeable batteries:present and beyond显示文摘Rechargeable batteries currently hold the largest share of the electrochemical energy storage market,and they play a major role in the sustainable energy transition and industrial decarbonization to respond to global climate change.Due to the increased popularity of consumer electronics and electric vehicles,lithium-ion batteries have quickly become the most successful rechargeable batteries in the past three decades,yet growing demands in diversified application scenarios call for new types of rechargeable batteries.Tremendous efforts are made to developing the next-generation post-Li-ion rechargeable batteries,which include,but are not limited to solid-state batteries,lithium–sulfur batteries,sodium-/potassium-ion batteries,organic batteries,magnesium-/zinc-ion batteries,aqueous batteries and flow batteries.Despite the great achievements,challenges persist in precise understandings about the electrochemical reaction and charge transfer process,and optimal design of key materials and interfaces in a battery.This roadmap tends to provide an overview about the current research progress,key challenges and future prospects of various types of rechargeable batteries.New computational methods for materials development,and characterization techniques will also be discussed as they play an important role in battery research. | Sen Xin Xu Zhang Lin Wang Haijun Yu Xin Chang Yu-Ming Zhao Qinghai Meng Pan Xu Chen-Zi Zhao Jiahang Chen Huichao Lu Xirui Kong Jiulin Wang Kai Chen Gang Huang Xinbo Zhang Yu Su Yao Xiao Shu-Lei Chou Shilin Zhang Zaiping Guo Aobing Du Guanglei Cui Gaojing Yang Qing Zhao Liubing Dong Dong Zhou Feiyu Kang Hu Hong Chunyi Zhi Zhizhang Yuan Xianfeng Li Yifei Mo Yizhou Zhu Dongfang Yu Xincheng Lei Jianxiong Zhao Jiayi Wang Dong Su Yu-Guo Guo Qiang Zhang Jun Chen Li-Jun Wan | 2024 | Science China Chemistry2024，67，1： | 0 |
| 12 | High-performance zinc-ion batteries enabled by electrochemically induced transformation of vanadium oxide cathodes显示文摘Rechargeable aqueous zinc-ion batteries(ZIBs) have become a research hotspot in recent years,due to their huge potential for high-energy,fast-rate,safe and low-cost energy storage.To realize good electrochemical properties of ZIBs,cathode materials with prominent Zn^(2+) storage capability are highly needed.Herein,we report a promising ZIB cathode material based on electrochemically induced transformation of vanadium oxides.Specifically,K_(2) V_6 O_(16)·1.5 H_(2) O nanofibers were synthesized through a simple stirring method at near room temperature and then used as cathode materials for ZIBs in different electrolytes.The cathode presented superior Zn^(2+) storage capability in Zn(OTf)_(2) aqueous electrolyte,including high capacity of 321 mAh/g,fast charge/discharge ability(96 mAh/g delivered in 35 s), high energy density of 235 Wh/kg and good cycling performance.Mechanism analysis evidenced that in Zn(OTf)_(2) electrolyte,Zn^(2+) intercalation in the first discharge process promoted K_(2) V_6 O_(16)·1.5 H_(2) O nanofibers to transform into Zn_(3+x)V_(2) O_7(OH)_(2)·2 H_(2) O nanoflakes,and the latter served as the Zn^(2+)-storage host in subsequent charge/discharge processes.Benefiting from open-framework crystal structure and sufficiently exposed surface,the Zn_(3+x)V_(2) O_7(OH)_(2)·2_H2 O nanoflakes exhibited high Zn^(2+) diffusion coefficient,smaller charge-transfer resistance and good reversibility of Zn^(2+) intercalation/de-intercalation,thus leading to superior electrochemical performance.While in ZnS04 aqueous electrolyte,the cathode material cannot sufficiently transform into Zn_(3+x)V_(2) O_7(OH)_(2)·2 H_(2) O thereby corresponding to inferior electrochemical behaviors.Underlying mechanism and influencing factors of such a transformation phenomenon was also explored.This work not only reports a high-performance ZIB cathode material based on electrochemically induced transformation of vanadium oxides,but also provides new insights into Zn^(2+)-storage electrochemistry. | Yang Li Wang Yang Wu Yang Yongfeng Huang Guoxiu Wang Chengjun Xu Feiyu Kang Liubing Dong | 2021 | Journal of Energy Chemistry2021，30，9： | 0 |
| 13 | Stable Zinc Anodes Enabled by Zincophilic Cu Nanowire Networks显示文摘Zn-based electrochemical energy storage(EES)systems have received tremendous attention in recent years,but their zinc anodes are seriously plagued by the issues of zinc dendrite and side reactions(e.g.,corrosion and hydrogen evolution).Herein,we report a novel strategy of employing zincophilic Cu nanowire networks to stabilize zinc anodes from multiple aspects.According to experimental results,COMSOL simulation and density functional theory calculations,the Cu nanowire networks covering on zinc anode surface not only homogenize the surface electric field and Zn^(2+)concentration field,but also inhibit side reactions through their hydrophobic feature.Meanwhile,facets and edge sites of the Cu nanowires,especially the latter ones,are revealed to be highly zincophilic to induce uniform zinc nucleation/deposition.Consequently,the Cu nanowire networks-protected zinc anodes exhibit an ultralong cycle life of over 2800 h and also can continuously operate for hundreds of hours even at very large charge/discharge currents and areal capacities(e.g.,10 mA cm^(-2)and 5 mAh cm^(-2)),remarkably superior to bare zinc anodes and most of currently reported zinc anodes,thereby enabling Zn-based EES devices to possess high capacity,16,000-cycle lifespan and rapid charge/discharge ability.This work provides new thoughts to realize long-life and high-rate zinc anodes. | Shiyin Xie Yang Li Xu Li Yujun Zhou Ziqi Dang Jianhua Rong Liubing Dong | 2022 | Nano-Micro Letters2022，14，2： | 0 |
| 14 | Reversible aqueous zinc-ion battery based on ferric vanadate cathode显示文摘Rechargeable aqueous zinc-ion batteries have attracted extensive interest because of low cost and high safety.However,the relationship between structure change of cathode and the zinc ion storage mechanism is still complex and challenging.Herein,open-structured ferric vanadate(Fe_(2)V_(4)O_(13))has been developed as cathode material for aqueous zinc-ion batteries.Intriguingly,two zinc ion storage mechanism can be observed simultaneously for the Fe2V4O13 electrode,i.e.,classical intercalation/deintercalation storage mechanism in the tunnel structure of Fe_(2)V_(4)O_(13),and reversible phase transformation from ferric vanadate to zinc vanadate,which is verified by combined studies using various in-situ and ex-situ techniques.As a result,the Fe_(2)V_(4)O_(13) cathode delivers a high discharge capacity of 380 mAh/g at 0.2 A/g,and stable cyclic performance up to 1000 cycles at 10 A/g in the operating window of 0.2-1.6 V with 2 mol/L Zn(CF_(3)SO_(3))_(2) aqueous solution.Moreover,the assembled Fe_(2)V_(4)O_(13)//Zn flexible quasi-solid-state battery also exhibits a relatively high mechanical strength and good cycling stability.The findings reveal a new perspective of zinc ion storage mechanism for Fe_(2)V_(4)O_(13),which may also be applicable to other vanadate cathodes,providing a new direction for the investigation and design of zinc-ion batteries. | Wang Yang Wu Yang Yongfeng Huang Chengjun Xu Liubing Dong Xinwen Peng | 2022 | Chinese Chemical Letters2022，33，10： | 0 |
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