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您的检索式：作者名="Wangchen Huo"
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| 1 | Anion intercalated layered-double-hydroxide structure for efficient photocatalytic NO remove显示文摘Due to the easily controllable interlayer anions, metal cation composition proportion and thickness, which is beneficial to modify surface chemical state and tune bandgap, layered double hydroxides(LDHs) have great promising potential for photocatalytic applications. In this study,we have successfully synthesized the ZnAl–LDH intercalated the single anion between ZnAl cationic interlayer without anionic impurities by using a facile calcining and reconstructing routes. The electron structure and surface chemical state of the prepared products have been investigated by combining the DFT calculation and experimental characterization methods. UV–vis DRS was used to certify the light absorption of the prepared products, and we performed the DFT calculation to demonstrate the density of state and activation of reactant. These results suggested that the ZnAl–LDH–CO3 possessed the more proper band structure and superior ability to activate NO and O2 for accelerating the photocatalytic NO oxidation activity. Moreover, the in situ DRIFTS with dynamically monitoring intermediates and products over the ZnAl–LDH–CO3 was adopted to declare the photocatalytic NO oxidized process during the photocatalytic reaction process. This work illustrated the influence of different interlayer anions to the electron structure and surface chemical state of ZnAl–LDH structure through the experimental verification combined DFT calculation and the photocatalytic NO oxidized process via in situ DRIFTS analyzing, which would provide a novel way to design and fabricate the efficient photocatalysis, and understand the reaction process. | Wangchen Huo Tong Cao Xiaoying Liu Weina Xu Biqin Dong Yuxin Zhang Fan Dong | 2019 | Green Energy & Environment2019，4，3： | 4 |
| 2 | Compulsive malposition of birnessite slab in 2D-Parallel birnessite on β-MnO_(2) networks for enhanced pseudocapacitance performances显示文摘High electrochemically active bimessite is always desirable pseudocapacitive material for supercapacitor.Here,two-dimensional(2D)compulsive malposition parallel bimessite standing on β-MnO_(2) interconnected networks have been designed.Due to the retrition of β-MnO_(2),compulsi ve malposition,slippage of MnO6 slab,occured in bimessite resulting in weaken bi nding force between bimessi te slab and interlayer cations,which enhanced their electrochemical performances.Additionally,the electrical conductivity of the structure was largely promoted by the 2D charge transfer route and double-exchange mechanism in bimessite,also leading to desirable electro-chemical properties.Based on the fraction of as-prepared nanostructure,the par all bimessite exhibited good pseudocapacitance performance(660 F g^(-1))with high rate capability.In addition,the asymmetrice supercapacitor assembled by reduced graphene oxide(RGO)and as-prepared nanostructure,which respectively served as the negative and positive eletrode,delivered an energy density of 33.1 Wh kg^(-1) and a mad mum power density of 64.0 kW kg^(-1) with excellent cyeling stability(95.8% after 10000 cycles).Finally,the study opens new avenwes for synthesizing high eletrochemically actiwe bimessite structure for high-performance energy storage devices. | Shijin Zhua Wangchen Huo Tian Wang Kailin Li Xiaoying Liu Junyi Ji Hongchang Yao Fan Dong Yuxin Zhang Lili Zhang | 2021 | Nano Materials Science2021，3，4： | 0 |
| 3 | Melamine sponge derived porous carbon monoliths with NiMn oxides for high performance supercapacitor显示文摘Supercapacitors with good electrochemical performance and flexibility are in great demand.In this paper,the concept of preparing 3D porous carbon monoliths via direct calcination of melamine sponge is presented.This preparation method is simple and has good control of the structure.Porous carbon composite nickel-manga nese oxides can be obtained by hydrothermal method followed with calcination.The electrochemical performances were tested and porous carbon monoliths with NiMn oxides exhibited a specific capacitance of 870 F/g in 1 mol/L KOH at a charge/discharge current density of 0.5 A/g and a capacity retention of 89.9% after 5000 times charge and discharge. | Qianyuan Shan Wangchen Huo Man Shen Chuan Jing Yan Peng Huayan Pu Yuxin Zhang | 2020 | Chinese Chemical Letters2020，31，9： | 0 |
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