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您的检索式：作者名="Thalappil Pradeep"
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| 1 | Mesoflowers:A New Class of Highly Effi cient Surface-Enhanced Raman Active and Infrared-Absorbing Materials显示文摘A method for the synthesis of a new class of anisotropic mesostructured gold material,which we call“mesoflowers”,is demonstrated.The mesoflowers,unsymmetrical at the single particle level,resemble several natural objects and are made up of a large number of stems with unusual pentagonal symmetry.The mesostructured material has a high degree of structural purity with star-shaped,nano-structured stems.The mesoflowers were obtained in high yield,without any contaminating structures and their size could be tuned from nano-to meso-dimensions.The dependence of various properties of the mesoflowers on their conditions of formation was studied.The near-infrared infrared(NIR IR)absorption exhibited by the mesoflowers has been used for the development of infrared filters.Using a prototypical device,we demonstrated the utility of the gold mesoflowers in reducing the temperature rise in an enclosure exposed to daylight in peak summer.These structures showed a high degree of surface-enhanced Raman scattering(SERS)activity compared to spherical analogues.SERS-based imaging of a single mesoflower is demonstrated.The high SERS activity and NIR IR absorption property open up a number of exciting applications in diverse areas. | Panikkanvalappil Ravindranathan Sajanlal Thalappil Pradeep | 2009 | Nano Research2009，2，4： | 5 |
| 2 | Two Distinct Fluorescent Quantum Clusters of Gold Starting from Metallic Nanoparticles by pH-Dependent Ligand Etching显示文摘Two fl uorescent quantum clusters of gold,namely Au25 and Au8,have been synthesized from mercaptosuccinic acid-protected gold nanoparticles of 45 nm core diameter by etching with excess glutathione.While etching at pH~3 yielded Au_(25),that at pH 7-8 yielded Au_(8).This is the fi rst report of the synthesis of two quantum clusters starting from a single precursor.This simple method makes it possible to synthesize well-defined clusters in gram quantities.Since these clusters are highly fl uorescent and are highly biocompatible due to their low metallic content,they can be used for diagnostic applications. | Madathumpady Abubaker Habeeb Muhammed Subramani Ramesh Sudarson Sekhar Sinha Samir Kumar Pal Thalappil Pradeep | 2008 | Nano Research2008，1，4： | 5 |
| 3 | Fluorescent Superlattices of Gold Nanoparticles:A New Class of Functional Materials显示文摘Fluorescent three-dimensional(3-D)superlattices of dansyl glutathione protected gold nanoparticles,with potential applications in molecular detection,have been synthesized at an air/water interface by controlling the pH of the nanoparticle suspension.The number of fluorophores per nanoparticle was calculated to be~127.Morphologies of the superlattice crystals were examined using scanning electron microscopy(SEM).Most of the crystals observed were triangular in shape.High-resolution transmission electron microscopy(HRTEM)and small angle X-ray scattering(SAXS)were used to study the packing of nanoparticles in these crystals.Both these studies showed that the nanoparticles were arranged in a face-centered cubic(fcc)pattern with a particle-particle distance(center-center)of~10.5 nm.Evolution of the crystal morphologies with time was also examined.The fluorescence properties of these triangles were studied using confocal fluorescence imaging and confocal Raman mapping,which were in good agreement with the morphologies observed by SEM.The superlattice exhibits near-infrared(NIR)absorption in the range 1100-2500 nm.Easy synthesis of such functional nanoparticle-based solids makes it possible to use them in novel applications.We utilized the fluorescence of dansyl glutathione gold superlattice crystals for the selective detection of bovine serum albumin(BSA),the major protein constituent of blood plasma,based on the selective binding of the naphthalene ring of the dansyl moiety with site I of BSA. | Edakkattuparambil Sidharth Shibu Madathumpady Abubaker Habeeb Muhammed Keisaku Kimura Thalappil Pradeep | 2009 | Nano Research2009，2，3： | 3 |
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