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1篇 您的检索式:作者名="Micaela Vannini"
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1Biobased Vanillic Acid and Ricinoleic Acid: Building Blocks for Fully Renewable Copolyesters显示文摘New fully biobased polyether/esters have been synthesized by a one-pot polymerization reaction of ricinoleic acid(RA),vanillic acid(VA)and ethylene carbonate(EC).In particular,EC selectively reacts with the phenolic group of VA to obtain in-situ 4-(2-hydroxyethoxy)-3-methoxybenzoate(EV),suitable for subsequent copolymerization with RA.The procedure was carried out in a single step,without any solvent.Chemical structure and thermal properties of the new materials were studied in order to explore relationships between composition and final performances.The combination of EV,bearing a rigid aromatic structure,with RA,characterized by high flexibility and potential biocidal activity,allows the production of a novel class of fully biobased aliphatic-aromatic polymers presenting tuneable thermal properties and suitable for a range of applications,for example,in active packaging and biomedical fields.Claudio Gioia Maria Barbara Banella Grazia Totaro Micaela Vannini Paola Marchese Martino Colonna Laura Sisti Annamaria Celli 2018Journal of Renewable Materials2018,6,1:0
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