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2篇 您的检索式:作者名="Lutong Shan"
    题名 作者 年代 出处 被引量
1Interfacial adsorption-insertion mechanism induced by phase boundary toward better aqueous Zn-ion battery显示文摘Biphasic and multiphasic compounds have been well clarified to achieve extraordinary electrochemical properties as advanced energy storage materials.Yet the role of phase boundaries in improving the performance is remained to be illustrated.Herein,we reported the biphasic vanadate,that is,Na_(1.2)V_(3)O_(8)/K_(2)V_(6)O_(16)·1.5H_(2)O(designated as Na0.5K0.5VO),and detected the novel interfacial adsorption-insertion mechanism induced by phase boundaries.Firstprinciples calculations indicated that large amount of Zn^(2+)and H^(+)ions would be absorbed by the phase boundaries and most of them would insert into the host structure,which not only promote the specific capacity,but also effectively reduce diffusion energy barrier toward faster reaction kinetics.Driven by this advanced interfacial adsorption-insertion mechanism,the aqueous Zn/Na_(0.5)K_(0.5)VO is able to perform excellent rate capability as well as long-term cycling performance.A stable capacity of 267 mA h g^(-1)after 800 cycles at 5 A g^(-1)can be achieved.The discovery of this mechanism is beneficial to understand the performance enhancement mechanism of biphasic and multiphasic compounds as well as pave pathway for the strategic design of highperformance energy storage materials.Lutong Shan Yiren Wang Shuquan Liang Boya Tang Yongqiang Yang Ziqing Wang Bingan Lu Jiang Zhou 2021InfoMat2021,3,9:8
2Investigation of sodium vanadate as a high-performance aqueous zinc-ion battery cathode显示文摘Due to the intrinsic advantages of nontoxicity, low-cost, and abundant resource of metallic zinc, aqueous zinc-ion batteries (ZIBs) have attracted universal interest [1,2]. Tremendous cathode materials have been exploited in aqueous ZIBs, such as manganese-based materials [3-11], Co-based materials [12,13] and vanadium-based materials [14-21].Binghong She Lutong Shan Huijie Chen Jiang Zhou Xun Guo Guozhao Fang Xinxin Cao Shuquan Liang 2019Journal of Energy Chemistry2019,28,10:2
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