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| 1 | Bimetallic Ru-Ni/TiO2 catalysts for hydrogenation of N-ethylcarbazole:Role of TiO2 crystal structure显示文摘Hydrogenation of N-ethylcarbazole(NEC),the hydrogen lean form of a liquid organic hydrogen carrier,on TiO2 supported Ru-Ni bimetallic catalysts is investigated.Crystal structure of TiO2 plays a critical role on the hydrogenation activity and selectivity towards fully hydrogenated product.Ru/anatase catalyst exhibits higher selectivity but lower reactivity compared to Ru/rutile catalyst.Ni addition significantly promotes the performance of Ru/anatase catalyst while causes severe performance deterioration of Ru/rutile catalyst.Commercial P25,a mixture of anatase and rutile phases in approximate ratio A/R1/4,is found to be the best TiO2 support for NEC hydrogenation.Ru/P25 catalyst outperforms both Ru/rutile and Ru/anatase and its activity can be further slightly improved by Ni addition.The unexpected synergism between the two different TiO2 phases for Ru based NEC hydrogenation catalysts is related to metal-support interaction and Ru-Ni interaction. | Hongen Yu Xue Yang Yong Wu Yanru Guo Shuan Li Wei Lin Xingguo Li Jie Zheng | 2020 | Journal of Energy Chemistry2020，29，1： | 7 |
| 2 | Recent advances on deoximation: From stoichiometric reaction to catalytic reaction显示文摘Deoximation reaction is one of the most important transformations in organic synthesis and for fine chemical production.Since oximes are easily synthesized from carbonyl compounds and are stable compounds,this reaction can be used for protection-deprotection,purification,and characterization of carbonyl compounds in organic synthesis,especially for the synthesis of medicines as well as the natural products.Moreover,because many oximes can be synthesized from non-carbonyl starting materials,the deoximation reaction is also widely used in the production of many carbonyl-contained fine chemicals.Deoximation methods by using stoichiometric reagents are mature and can produce the related carbonyl products in very high yield with broad substrate application scopes.But for environment-protection consideration as well as the production cost controlling purpose in fine chemical industry,developing catalytic deoximation methods is the trend of the field and there are a series of references on this topic in recent years.This short review summarized recent advances on the development of deoximation methods from stoichiometric reaction to catalytic reaction and the mechanisms of some important transformations were discussed in detail for reader reference. | Yinghao Zheng Aiqiong Wu Yangyang Ke Hongen Cao Lei Yu | 2019 | Chinese Chemical Letters2019，30，5： | 5 |
| 3 | eGPS 1.0: comprehensive software for multi-omic and evolutionary analyses显示文摘It has become increasingly challenging for researchers to analyze the exponentially expanding amount of multi-omic data.Here,we describe multi-functional software named evolutionary GenotypePhenotype Systems(eGPS)that enables users to perform comprehensive multiomic and evolutionary analyses.The eGPS combines the power of cloud computing and the advantage of desktop application,has a user-friendly graphic interface and is highly interactive. | Dalang Yu Lili Dong Fangqi Yan Hailong Mu Bixia Tang Xiao Yang Tao Zeng Qing Zhou Feng Gao Zhonghuang Wang Ziqian Hao Hongen Kang Yi Zheng Hongwei Huang Yuzhang Wei Wei Pan Yaochen Xu Junwei Zhu Shilei Zhao Ciran Wang Pengyu Wang Long Dai Mushan Li Li Lan Yiwei Wang Hua Chen Yi-Xue Li Yun-Xin Fu Zhen Shao Yiming Bao Fangqing Zhao Luo-Nan Chen Guo-Qing Zhang Wenming Zhao Haipeng Li | 2019 | National Science Review2019，6，5： | 4 |
| 4 | Organotellurium catalysis-enabled utilization of molecular oxygen as oxidant for oxidative deoximation reactions under solvent-free conditions显示文摘Catalyzed by commercially available(PhTe)2, molecular oxygen could be utilized as the mild, cheap and safe oxidant for oxidative deoximation reactions under solvent-free conditions. As the first report on organotellurium-catalyzed deoximation reaction, this work not only provides an efficient deoximation method, but also discloses new features of tellurium catalyst different from those of the organoselenium catalysts. | Xin Deng Hongen Cao Chao Chen Hongwei Zhou Lei Yu | 2019 | Science Bulletin2019，64，17： | 3 |
| 5 | An unexpected generation of magnetically separable Se/Fe3O4 for catalytic degradation of polyene contaminants with molecular oxygen显示文摘Selenization of Fe2O3 with NaHSe led to Se/Fe3O4.The unexpected generation of Fe3O4 attributed to the reduction conditions of the reaction,and the resulted magnetic features of the material facilitated its separation in practical applications.Owning to the synergistic effect of Se with Fe,the material was especially active to catalyze the oxidative C=C scission using O2 as mild oxidant.The technique has been successfully applied in polyene degradation project,which is of profound practical values for the treatment of the polyene pigment pollution and may be applied in the food and pha rmaceutical industry. | Xingyu Chen Jingfei Mao Chuang Liu Chao Chen Hongen Cao Lei Yu | 2020 | Chinese Chemical Letters2020，31，12： | 2 |
| 6 | Beta-endor- phin ameliorates synovial cell hypelfunction in the collagen-in- duced arthritis rat model by specific downregulation of' NF-kappa B activity 显示文摘 | YIN Hongen ZHANG Fengchun YU Mengxue | 2005 | Neuroendocrinology2005，81，1： | 1 |
| 7 | Synthesis of selenium-doped carbon from glucose:An efficient antibacterial material against Xcc显示文摘Se/C as a novel carbon-based biomaterial was prepared by using cheap and abundant glucose as the carbon source.It was highly active and could well restrain Xanthomonas campestris pv.campestris(EC50=4.7403 μg/mL),a very harmful germ causing the devastating cabbage black rot disease and resulting in huge economic losses.As a type of carbon material insoluble in wate r,Se/C is bio-compatible and can adhere onto the leaves of the plants to allow a slow and sustained release of its efficacy,affording an efficient method for the cabbage black rot disease prevention and cure.This work as the first report on the bioactivity studies of Se/C significantly expands the application scopes of the selenium-containing materials and may draw continuous attentions from a broad field. | Hongen Cao Yufan Yang Xijun Chen Jian Liu Chao Chen Shuzhong Yuan Lei Yu | 2020 | Chinese Chemical Letters2020，31，7： | 1 |
| 8 | Synergistic effect of T80/B30 vesicles and T80/PN320 mixed micelles with Se/C on nasal mucosal immunity显示文摘Selenium doped carbon(Se/C),an easily fabricated material,was found to be bio-active and it can serve as an adjuvant to enhance the immune effect of Tween 80/Brij 30(T80/B30)vesicles and Tween 80/polymer cationic surfactant PN320(T80/PN320)mixed micelles.The synergistic effect of the combination of T80/B30 vesicles and T80/PN320 mixed micelles with Se/C on nasal mucosal immunity was studied in this work,which might provide theoretical basis for developing the related new adjuvant for nasal immunization of recombinant protein,peptide and split protein vaccine.Since both selenium and carbon were bio-compatible elements,Se/C might be safe for practical applications,and this was also reflected by the low hemolytic activity of the materials.This work not only reports an efficient protocol for adjuvant development,but also significantly expands the application scope of selenium chemistry. | Hongen Cao Ruonan Ma Sainan Chu Juqun Xi Lei Yu Rong Guo | 2021 | Chinese Chemical Letters2021，32，9： | 0 |
| 9 | Nonstoichiometric Yttrium Hydride–Promoted Reversible Hydrogen Storage in a Liquid Organic Hydrogen Carrier显示文摘N-Ethylcarbazole(NEC)is one of the most promising liquid organic hydrogen carriers(LOHCs),but its application is limited by sluggish kinetics due to lack of high-efficiency,low-cost catalysts.This work reports a cobalt(Co)-based catalyst promoted by nonstoichiometric yttrium hydride(YH_(3−x))to achieve high-efficiency,reversible hydrogen storage in NEC,with>5.5 wt%reversible hydrogen storage capacity could be achieved below 473 K,and with good kinetics.The YH_(3−x)-promoted Co-based catalyst is the first non-noble metal catalyst with high activity for NEC hydrogenation and 12H-NEC dehydrogenation reactions.A mechanistic study suggests that YH_(3−x)facilitates the reversible hydrogen transfer both in the hydrogenation and the dehydrogenation reactions.The nonstoichiometric YH_(3−x)contained both lattice H and H vacancies with tunable H chemical potential serve as the H donor and H acceptor for reversible hydrogen transfer.Our results support the practical application of LOHCs and inspire new approaches for the utilization of conventional metal hydrides to promote versatile H transfer reactions. | Yong Wu Yanru Guo Hongen Yu Xiaojing Jiang Yuxuan Zhang Yue Qi Kai Fu Lei Xie Guoling Li Jie Zheng Xingguo Li | 2021 | CCS Chemistry2021，3，3： | 0 |
| 10 | Ta-doped modified Gd2O3 film for a novel high k gate dielectric显示文摘Gadolinium oxide(Gd2O3) film has potential as a candidate gate dielectric to replace Hf O2. In this work,we provide a simple method by trace Ta(~1%) doping to significantly improve the dielectric properties of Gd2O3 film. And effects of annealing temperatures of Ta-doped Gd2O3(GTO) films are investigated in detail. Results show that GTO film annealed at 500℃ exhibits excellent performance as a novel gate dielectric material for integrated circuit, showing a small surface roughness of 0.199 nm, a large band gap of 5.45 e V, a high dielectric constant(k) of 21.2 and a low leakage current density(Jg) of 2.10 × 10^-3A/cm^2.All properties of GTO films are superior to pure Gd2O3 films and these GTO films meet the requirements for next-generation gate dielectrics. In addition, impedance spectrum is first used to analyze the equivalent circuit of GTO based metal-oxide-semiconductor(MOS) capacitors, which represents a new insight to understand observed electrical behaviors. | Shuan Li Yanqing Wu Guoling Li Hongen Yu Kai Fu Yong Wu Jie Zheng Wenhuai Tian Xingguo Li | 2019 | Journal of Materials Science & Technology2019，35，10： | 0 |
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