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| 1 | Re-Os isotopes and PGE geochemistry of black shales and intercalated Ni-Mo polymetallic sulfide bed from the Lower Cambrian Niutitang Formation, South China显示文摘The Lower Cambrian Niutitang Formation consists of a thick black shale sequence with a regionally distributed conformable Ni Mo polymetallic sulfide horizon and a chert bed at its basal strata on theYangtze Platform, South China. In this paper, we discuss all available data on Re Os isotopes and Platinum Group Element (PGE) distribution pattern of the Ni Mo polymetallic sulfide ore and its host rocks (black shales, cherts, and phosphorites) from Guizhou and Hunan provinces. Our results show that the black shales and the Ni Mo sulfide ore have a high initial 187 Os/ 188 Os ratio of 0.78~0.86, indicating that the Early Cambrian ocean across the Yangtze Platform had a highly radiogenic Os value. This ratio is slightly lower than but still similar to present day seawater, possibly as a result of high continental weathering at that time. The Ni Mo sulfide ore yields a Re Os isochron of 537±10 Ma (MSWD=11.9), possibly representing the depositional age of the Niutitang Formation. The chondrite normalized PGE pattern, Pt anomaly (Pt/Pt *), Pt/Pd, Ir/Pd, Au/Ir and Re/Mo ratios of the Ni Mo sulfide ore and its host rocks from South China indicate a varying source contribution of the PGE and other metals for different rocks. It is suggested that the cherts and Ni Mo sulfide ore may have a significant proportion of PGE and probably other metals deriving from submarine hydrothermal fluids with a mantle signature. | JIANG Shaoyong*, YANG Jinghong, LING Hongfei, FENG Hongzhen, CHEN Yongquan and CHEN Jianhua(State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing 210093, China) | 2003 | Progress in Natural Science:Materials International2003，13，10： | 78 |
| 2 | 黑色页岩与大洋缺氧事件的Re-Os同位素示踪与定年研究显示文摘地质历史中发育多次大规模的大洋缺氧事件并伴随有巨量的黑色页岩沉积, 对这些大洋缺氧事件发生时限及成因机制的研究已成为当前国际古海洋学研究的一个前沿领域。开展对大洋缺氧事件的研究,有助于了解古海洋演化、地球系统变化和地球其他圈层对生物圈的影响,以及金属成矿、油气形成及生烃环境。因此近年来人们从古海洋、古气候、古地理、古生物、大地构造和地质地球化学等学科,积极开展对大洋缺氧事件的研究。对大洋缺氧事件进行准确定年则是研究工作开展的首要任务之一;而如果用于定年的同位素体系能同时提供相关的环境变迁信息,则更加有利于我们对缺氧事件成因机制的认识。Re Os同位素作为近年来发展起来的一种新的同位素技术方法,恰好适用于对富有机质沉积岩和黑色页岩的定年,可以获得精确的地层沉积年龄,同时利用这些海洋沉积物的Os同位素比值还可获得古海水的Os同位素组成及随时间的演化规律。在中国华南地区新元古代—早古生代发育有多幕次的大洋缺氧事件和黑色页岩的巨厚沉积和广泛分布,利用Re Os同位素研究,不但可以精确厘定这些事件发生的时限,而且可以有效示踪当时的古海洋环境。 | 杨競红 蒋少涌 凌洪飞 陈永权 | 2005 | 地学前缘2005，12，2： | 38 |
| 3 | 塔里木盆地寒武系层状硅质岩与硅化岩的元素、δ^(30)Si、δ^(18)O地球化学研究显示文摘塔里木盆地寒武系发育层状硅质岩和硅化岩,层状硅质岩主要发育于塔东下寒武统深水沉积相区;硅化岩发育于塔东上寒武统斜坡沉积区与西部台地区寒武系白云岩中。根据显微结构特征,可将硅化岩分为放射状硅化岩与交代残余结构硅化岩两种。分析结果表明,层状硅质岩在Al-Fe-Mn三元图中位于正常海水沉积硅质岩区内,在微量元素平均地壳标准化图解上显示平缓右倾的特征;层状硅质岩Si同位素组成δ30Si为0.9‰~1.4‰,O同位素组成δ18O为21.4‰~24.4‰,与沉积型硅质岩相吻合,指示了正常海水沉积成因。硅化岩区别于层状硅质岩的典型特征是具有高U异常的特征;罗西斜坡放射状硅化岩具有较高的微量元素和稀土元素含量(∑REE为18.8~96.9μg/g)与较低的Si、O同位素值(δ18O和δ30Si值分别为15.8‰和1.7‰);西部台地区交代残余结构硅化岩具有较低微量元素和稀土元素含量(∑REE为0.58~2.61μg/g)与较高的δ30Si(1.0‰~3.8‰)、δ18O(21.6‰~27.0‰)值特征。盆地东西部硅化岩的地球化学差异可能与硅化流体的温度差异有关,罗西斜坡放射状硅化岩硅化温度相对更高;另一方面,硅化过程对H430SiO4选择性较高,因而形成的交代石英具有较高的δ30Si值。根据古城4井硅化岩包裹体均一温度与交代石英的O同位素值计算得到交代流体的δ18O值为9.1‰,该值与酸性岩浆水的δ18O值相似,指示了硅化流体可能来自于岩浆或变质水;以δ18O值(9.1‰)作为西部台地区硅化流体的O同位素值,计算得到西部台地区硅化岩硅化流体温度为101.3~158.5℃。根据石英O同位素温度计计算的硅化流体温度呈东高西低的趋势,指示了硅化流体可能来自台地东部。 | 陈永权 蒋少涌 周新源 杨文静 韩利军 | 2010 | 地球化学2010，39，2： | 32 |
| 4 | 天柱大河边重晶石矿床铅同位素特征及来源探讨显示文摘对取自天柱大河边重晶石矿床的重晶石样品和含方铅矿黑色页岩样品进行了铅同位素测定与研究。结果表明,在Zartman铅构造模式图中,重晶石矿石、含方铅矿黑色页岩和黑色页岩有大致相同的铅同位素分布区,均沿上地壳铅演化线分布,表明它们之间具有同源关系;重晶石矿石及其赋矿黑色页岩的铅同位素组成与基底地层的铅同位素组成在Zartman铅构造模式图中具有完全不同的分布范围,表明重晶石矿石中的铅不大可能来源于基底地层;结合重晶石矿石及其赋矿黑色页岩的铅同位素组成在Zartman铅构造模式图和Δγ-Δβ铅来源分类图的分布,天柱大河边重晶石矿床的铅主要具上地壳铅、壳幔混合的俯冲带铅和热水沉积作用铅的混合来源特点,这为天柱大河边重晶石矿床的热水沉积成因提供了铅同位素证据。 | 夏菲 马东升 潘家永 孙占学 曹双林 陈少华 聂文明 吴凯 刘莉 | 2005 | 地球化学2005，34，5： | 29 |
| 5 | Paleoceangraphic significance of redox-sensitive metals of black shales in the basal Lower Cambrian Niutitang Formation in Guizhou Province, South China显示文摘Black shales of the Lower Cambrian Niutitang Formation occur widely on the Yangtze Platform. In this study, we analyzed black shales from two sections (Zhongnan and Zhijin) in Guizhou Province. The redox-sensitive metal concentration and distribution of black shales from the two sections provide good evidence for the anoxic conditions of the basal Cambrian ocean on the Yangtze Platform. Our geochemical data suggest that the black shales from the Zhongnan section may have deposited in a more strongly anoxic environment than the black shales in the Zhijin section. | YANGJinghong JIANGShaoyong LINGHongfei FENGHongzhen CHENYongquan CHENJianhua | 2004 | Progress in Natural Science:Materials International2004，14，2： | 26 |
| 6 | 华南寒武纪海洋中沉积矿床及其古环境显示文摘寒武纪早期是华南的一个重要的沉积矿床形成阶段。在华南扬子板块下寒武统黑色岩系中产有大量的金属及非金属矿床,其中倍受关注的矿床有Ni Mo PGE多金属硫化物矿床、磷矿床与重晶石矿床。Ni Mo PGE多金属硫化物矿床的形成可能与海底热液喷流作用有关,成矿元素除海水源外,有部分来自深部热液;磷矿床形成于特定的浅海环境,成矿物质的聚集可能与有机质和含铁胶体有关;重晶石矿床的形成也与海底热液和有机质有关。这些矿床保存了大量的古海洋信息,对其进行深入研究可以揭示华南寒武纪大爆发时期的古海洋环境变化特征。 | 陈永权 蒋少涌 凌洪飞 杨竞红 陈建华 | 2005 | 海洋地质与第四纪地质2005，25，1： | 18 |
| 7 | 贵州江口平引老堡组顶部的锆石SHRIMP年龄与对比意义显示文摘华南扬子地台下寒武统(相当于寒武系新划分方案的纽芬兰统和第二统)对于揭示早期生命演化、全球生物地球化学循环以及古海洋环境变化等一系列全球性的重大科学问题具有重要研究价值.其中,对该区下寒武统进行精确的绝对年龄标定是多学科交叉研究中至关重要的一个方面.对最近于贵州江口平引剖面老堡组顶部发现的钾质斑脱岩中锆石进行SHRIMPU-Pb年代学研究,其年龄结果为(536±5)Ma(MSWD=0.75),初步认为该钾质斑脱岩可以与前人集中研究的云南梅树村剖面朱家菁组中谊村段中部(第5层)钾质斑脱岩进行区域对比,这一对比结果显示过去仅发现于内部台地浅水环境的第5层钾质斑脱岩在扬子地台较深水环境亦存在沉积记录.平引剖面老堡组顶部钾质斑脱岩的年龄结果直接约束了该剖面牛蹄塘组底部Ni-Mo多金属层的绝对年龄应年轻于(536±5)Ma,表明将Ni-Mo多金属层作为前寒武系-寒武系界线是不适宜的.结合区域对比及碳同位素化学地层学全球对比研究成果,认为朱家菁组中谊村段中部(第5层)及其相当层位的钾质斑脱岩、石岩头组底部及其可对比层位的钾质斑脱岩以及Ni-Mo多金属层可作为扬子地台区域地层对比的三个重要标志层,它们相互一致的绝对年龄初步构建了华南下寒武统的时间框架. | 周明忠 罗泰义 刘世荣 钱志宽 邢乐才 | 2013 | 中国科学:地球科学2013，43，7： | 14 |
| 8 | 湘西花垣李梅铅锌矿床C、O、S、Pb同位素特征及成矿物质来源显示文摘李梅铅锌矿床位于扬子地块的东南缘,是湘西-鄂西成矿带花垣矿田中较早发现的超大型铅锌矿床之一,矿体呈层状、似层状产于寒武系清虚洞组藻灰岩中。文章通过对其进行C、O、S、Pb同位素地球化学及流体包裹体激光拉曼的研究,探讨了成矿流体和成矿物质的来源及演化。研究结果表明:成矿期热液方解石的δ^(13)CPDB为-2.79‰~1.11‰,δ^(18)OSMOW为14.59‰~23.05‰,表明成矿流体中的CO_2主要来自于寒武系碳酸盐岩的溶解,部分成矿期及成矿后的热液方解石与有机质的热化学还原作用有关。激光拉曼研究显示包裹体气相成分中含大量的CH_4、H_2S、N_2及其他烃类,推测已经演化到高成熟阶段的有机质可能以古油气藏的形式参与了成矿作用,闪锌矿中气态含碳质沥青包裹体的出现暗示有机质的热化学还原反应参与了铅锌成矿过程。矿石中硫化物的δ^(34)SCDT值为+26.30‰^+34.66‰,平均值为+30.52‰,表明还原S主要来自成矿流体中海水硫酸盐充分的热化学还原作用。矿石硫化物的Pb同位素组成变化范围较小,^(206)Pb/^(204)Pb、^(207)Pb/^(204)Pb、^(208)Pb/^(204)Pb分别为17.999~18.235、15.584~15.789、38.147~38.576,推测成矿物质主要来源于元古界浅变质基底板溪群和寒武系下统牛蹄塘组黑色页岩,部分来自于清虚洞组赋矿围岩。 | 胡太平 王敏芳 丁振举 何谋 王彦博 郭晓南 | 2017 | 矿床地质2017，36，3： | 12 |
| 9 | SHRIMP zircon age for a K-bentonite in the top of the Laobao Formation at the Pingyin section,Guizhou,South China显示文摘The Lower Cambrian on the Yangtze Platform in South China(internationally equivalent to the Nerreneuvian and 2nd series of the Cambrian)is valuable for understanding the early evolution of life,the global biogeochemical circles,and the major changes of the ocean.In particular,a precise radiometric calibration of the Lower Cambrian of this region is a critical realm in its multidisciplinary studies.A SHRIMP U-Pb geochronology study of the K-bentonite in the topmost Laobao Formation at the Pingyin section,Guizhou,South China yielded an age of 536±5 Ma(MSWD=0.75),suggesting that the K-bentonite here can be correlated with the intensely studied K-bentonite within the middle Zhongyicun Member(Bed 5)of the Zhujiaqing Formation at the Meishucun section in Yunnan.Such a regional correlation result reveals that the Bed 5 K-bentonite also extends into deeper-water environments rather than being deposited merely in the shallow platform interior of the Yangtze Platform.The age of the K-bentonite at the Pingyin section also implies that its overlying polymetallic Ni-Mo layer should be younger than 536±5 Ma.Hence the previous placement of the Precambrian/Cambrian boundary at this layer is inappropriate.Combined with the results of stratigraphic correlations,it is suggested that the K-bentonites in the middle Zhongyicun Member of the Zhujiaqing Formation(or the equivalents)and the base of the Shiyantou Formation(or its equivalents),together with the polymetallic Ni-Mo layer,serve as three important marker beds.Their self-consistent radiometric ages have established an improved geochronologic framework for the Lower Cambrian in South China. | ZHOU MingZhong LUO TaiYi LIU ShiRong QIAN ZhiKuan XING LeCai | 2013 | Science China Earth Sciences2013，56，10： | 10 |
| 10 | New Re-Os Isotopic Constrains on the Formation of the Metalliferous Deposits of the Lower Cambrian Niutitang Formation显示文摘The Terreneuvian Epoch(541–521 Ma)is also an important period for metallogenesis in South China, as was represented by the widespread occurrences of Ni-Mo polymetallic layers on the antecedent shallow platform margin and the V-enriched black shales in deeper slope-basin settings. In this study, we have measured Re-Os isochron ages of Ni-Mo polymetallic layers(Songlin, Niuchang, Sancha, Chuanpengwan), V-rich black shales(Bahuang), and non-metalliferous black shales(Shuidong) in the basal Niutitang Formation in Guizhou and Hunan province, South China. The Ni-Mo polymetallic layers and V-enriched black shales have similar Re-Os isochron ages, suggesting concurrent deposition of these two types of metalliferous ores. This suggestion is consistent with the traditional stratigraphic correlation by using the nodular phosphorite bed directly underlying these metalliferous layers as a stratigraphic marker. Furthermore, the metalliferous ores and non-metalliferous black shales have similar initial ^(187)Os/^(188) Os ratios of 0.8–0.9, arguing for a dominant seawater origin with minor contribution of hydrothermal activity. Furthermore, Re-Os isotopic data also imply that Ni-Mo and V ore might have derived from the same source. We suggest that the spatial distribution of metalliferous ores can be explained by the development of non-sulfidic anoxic-suboxic wedge(NSASW) in the slope-basin and sulfidic wedge in the previous platform margin. Upwelling of deep water first transects the mildly reduced, organic rich NSASW, in which V(V) is reduced to V(IV), and is preferentially removed from seawater by organometallic complex formation. As a result, V-rich black shale deposits in the slope-basin of Yangtze Platform. Further movement of deep water into the sulfidic platform margin results in Ni-Mo polymetallic layer formation. | Yong Fu Lin Dong Chao Li Wenjun Qu Haoxiang Pei Wenlang Qiao Bing Shen | 2016 | Journal of Earth Science2016，27，2： | 9 |
| 11 | 贵州开阳磷矿地区下寒武统牛蹄塘组地层层序及其As、Sb、Au、Ag丰度异常与赋存状态研究显示文摘贵州开阳磷矿地区出露较为完整的下寒武统黑色岩系层序,这套黑色岩系中富含多种金属元素,但目前对岩系中主要低温成矿元素As、Sb、Au、Ag的地球化学背景异常与分布规律了解极少,对其形成背景与赋存状态无法进行深入讨论。本文以开阳磷矿地区下寒武统牛蹄塘组黑色岩系剖面作为研究对象,通过详细的野外地质调查、系统采样并进行地球化学分析、全岩硫同位素分析及黄铁矿电子探针分析,划分了详细的牛蹄塘组地层层序,对主要低温成矿元素(As、Sb、Au、Ag)的丰度异常、富集特征及赋存状态进行了研究,结果表明,黑色岩系中普遍富集As、Sb、Ag三种主要低温成矿元素,Au也在大部分层位富集。四种元素具有层控性的特点,在牛蹄塘组下部有机质含量较高的黑色白云质粉砂质页岩和黑色页岩层位中具有较高的元素丰度异常,在泥岩和粉砂岩混合层位元素丰度异常较低,钙质成分含量较高的层位元素含量较低。黄铁矿是黑色页岩中金的主要赋存矿物,也是Sb的重要赋存矿物,同时是Ag和As的次要赋存矿物;不同类型的黄铁矿,元素富集规律也不相同:As、Ag更容易富集在不规则集合体和草莓状黄铁矿中,Sb和Au则在散布的单颗粒黄铁矿中富集系数最高。 | 张岳 颜丹平 赵非 李旭拓 邱亮 张翼西 | 2016 | 岩石学报2016，32，11： | 8 |
| 12 | 云南下寒武统黑色岩系矿床研究现状及相关找矿问题探讨显示文摘云南地区下寒武统黑色岩系分布广泛,组成多为黑色、灰黑色的页岩、炭质页岩、砂质页岩及硅质岩等。在黑色岩系中伴有镍、钼、铀、钒、银、硒、铂、钯、铜,铅、锌等元素的成矿和矿化富集。由于其特殊的形成时代及特殊的多金属组合特点,黑色岩系矿床一直是地质学家研究的热点。本文在收集分析国内外大量文献资料基础上,系统地对国内外黑色岩系及矿床分布、矿种及赋存形式、成矿模式、沉积环境进行了综述,总结了云南黑色岩系及矿床研究的现状及成果,指出了云南黑色岩系找矿勘查方面应注意的几个关键性技术问题。 | 陈艳霞 崔银亮 廖剑锋 田茂军 姜永果 | 2013 | 矿物学报2013，33，4： | 8 |
| 13 | 贵州寒武系底部黑色岩系成矿序列划分与对比显示文摘一系列的黑色岩系多金属矿床广泛分布于中国南方地区寒武系底部,前人对多金属矿特征、成因等方面进行许多研究,但对Mo-Ni、V、P和Ba矿的成矿顺序研究较少。本文对云南德泽、贵州纳雍-坝黄-天柱及湘西柑子坪等地区的寒武系底部黑色岩系多金属矿的成岩成矿环境、矿石矿物微观特征、成矿地球化学等方面研究,结合元素富集层出现先后可将寒武系底部成矿作用自下而上分为四个成矿序列:即磷矿成矿序列、重晶石矿成矿序列、钒矿成矿序列、镍钼矿序列。同时,根据岩石组合、矿物组合、含矿性等特征,将贵州境内Mo-Ni、V、P和Ba矿床划分为三个成矿区,即纳雍-遵义-福泉黔中镍钼成矿区、铜仁-镇远-岑巩黔东南钒(镍钼)成矿区、天柱-新晃重晶石成矿区。 | 李军 高军波 魏怀瑞 陈述云 吴桐 高磊 杨瑞东 | 2019 | 地质与勘探2019，55，2： | 7 |
| 14 | Marine Redox Conditions in the Early Cambrian Ocean: Insights from the Lower Cambrian Phosphorite Deposits, South China显示文摘It is generally considered that a significant change in oceanic redox conditions occurred during the Ediacaran–Cambrian transition. However, there are currently two major conflicting views on the degree of oxygenation of deep water(oxic vs. ferruginous) during this interval. To date, the oxygenation conditions of the Early Cambrian ocean have not been well constrained. The oxygenation magnitude and mechanism of the Early Cambrian ocean could be critical to the significant biological evolution of the 'Cambrian Explosion'. To constrain the Early Cambrian oceanic redox environment, we conducted an integrated study on iron and sulfur isotopes and redox-sensitive elements(Mo, U, and V) of Lower Cambrian phosphorite deposits from two shallow sections(Meishucun and Gezhongwu) and a deeper water section(Zunyi) from the Yangtze Platform, South China. The near zero δ^(56)Fe values from the two shallow sections studied here reflect oxic conditions in the lower phosphorite deposition. An obvious positive shift in δ^(56)Fe and redox-sensitive element content was observed in the middle parts of the two shallow water sections, which might reflect loss of light iron by dissimilatory iron reduction during early diagenesis under suboxic shallow water in the platform. However, the highly positive δ^(56)Fe values in the deep section could reflect a lower oxidation degree of dissolved Fe(II) under anoxic deep water. The data suggest redox-stratified oceanic conditions during the Early Cambrian, in which completely oxygenated shallow water(platform) coexisted with anoxic deep water(slope). We propose that prolonged upwelling of dissolved organic carbon(DOC)-, Fe(II)- and phosphorus-rich anoxic deep water in a redox-stratified ocean could have increased exchange with the open ocean, resulting in major phosphorite deposition in oxic-suboxic conditions. The progressive oxygenation of the ocean may have facilitated the Early Cambrian biotic diversification. | Haifeng Fan Hanjie Wen Xiangkun Zhu | 2016 | Journal of Earth Science2016，27，2： | 6 |
| 15 | Stratigraphic implications of Sinian-Early Cambrian volcanic ash beds on the Yangtze Platform显示文摘Volcanic ash beds from shallow to deep water facies strata of the Sinian Early Cambrian (Meishucunian) on the Yangtze Platform consist of bentonites and tuffites which are readily recognized in the field by their physical features and confirmed by geochemical analyses. Geochemistry suggests that the volcanic ash beds in Meishucunian time are rhyolite and rhyodacite while those in the Qiongzhusian and Sinian are andesite and trachyandesite. The ash beds in the time equivalent strata, even in different areas display rather similar geochemical features, whereas the ash beds in different strata even in the same areas show large chemical difference. The results suggest that these ash beds can be used for intra and extra basinal correlations of the Sinian Early Cambrian interval on the Yangtze Platform. Additionally, these ash beds suggest high potentials for further U Pb dating strategies. | ZHANGJunming ZHUMaoyan YANGAihua LIGuoxiang YANGJinghong ChristophHEUBECK | 2004 | Progress in Natural Science:Materials International2004，14，1： | 5 |
| 16 | Isotopic compositions of small shelly fossil Anabarites from Lower Cambrian in Yangtze Platform of South China: Implications for palaeocean temperature显示文摘Anabarites belong to small shelly fossils (SSF), which occur widely in the Lower Cambrian strata of Yangtze Platform in South China. They are phosphate shell in composition and represent the earliest stage of the Cambrian bioradiation of Bilateria, the so-called 'Cambrian Explosion'. In this study, we attempted to separate Anabarites fossils from Lower Cambrian dolostones, and we obtained samples of both the fossils (SSF) and the granular phosphates (GP). Isotopic analyses were performed on samples of SSF, GP, and matrix dolostone (DH-23). The results showed that the δ30Si values of the quartz filling in fossils celoms, and the siliceous materials in granular phosphates are -0.6‰ and -0.7‰, which is different from normal sedimentary siliceous rocks from the Lower Cambrian strata (0—0.7‰) as reported by Li et al., but is consistent with the data for siliceous rocks and cherts of submarine hydrothermal origin. It is likely that a later hydrothermal replacement could have taken place in the SSF-bearing sedimentary rocks. The oxygen isotope values of the phosphate of SSF and GP are 16.8‰ and 17.0‰, respectively. These are significantly higher than the Neoproterozoic phosphate ores (10.9‰—13.9‰) as reported by Ling et al., hence, late diagenesis and hydrothermal replacement may not have caused a significant change in the oxygen isotope compositions of the small shelly fossils, and the calculated temperatures (25.4—26.3℃) for palaeo-seawater using a SSF phosphate oxygen isotope thermometer are therefore considered here as the upper limit of seawater temperature in the Early Cambrian ocean of the Yangtze Platform. | Chen Yongquan Jiang Shaoyong Ling Hongfei Yang Jlnghong Wan Defan | 2007 | Progress in Natural Science:Materials International2007，17，10： | 4 |
| 17 | 黑色页岩的Re-Os同位素定年显示文摘Re-Os同位素是近年来发展起来的一种新的同位素技术,既可用于定年又能用于示踪。国际上如何对沉积岩进行精确定年一直是个难题。近年来的研究表明,Re-Os同位素可以用于黑色页岩的精确定年,同时可用于示踪古海洋环境。笔者对华南下寒武统牛蹄塘组黑色页岩开展了Re-OS同位素定年研究,获得的等时线年龄为537±10Ma。 | 杨競红 蒋少涌 凌洪飞 陈永权 冯洪真 | 2005 | 地球学报2005，26，B09： | 4 |
| 18 | 贵州铜仁瓦屋牛蹄塘组下部凝灰岩锆石年龄及其地质意义显示文摘运用LA-ICP-MS技术,对牛蹄塘组凝灰岩夹层进行锆石U-Pb年代学测试,获得凝灰岩的年龄为546.3±4.3 Ma,该年龄与Chen等(2003)运用Pb-Pb淋滤法获得的遵义中南和织金牛蹄塘组黑色页岩的沉积年龄(531±24 Ma)在误差范围内一致,与卓皆文等(2009)运用锆石U-Pb年代学获得铜仁坝黄震旦纪老堡组顶部晶屑凝灰岩的年龄(556±5Ma)比较,二者与地层沉积时序一致,年龄跨度也很合理;与许多学者对华南早寒武世早期“多元素富集层”的Re-Os同位素定年结果一致,暗示“多元素富集层”的成矿物质来源可能与这期火山作用密切相关。 | 牟军 强希润 覃永军 王安华 张厚松 | 2022 | 贵州地质2022，39，1： | 0 |
| 19 | 遵义松林下寒武统钾质斑脱岩SHRIMP U-Pb锆石年龄及其地质意义显示文摘 遵义松林地区广泛出露前寒武系及寒武系,是国际上研究前寒武纪-寒武纪过渡时期生物演化、古环境变迁及成矿事件的重要窗口之一.…… | 周明忠 罗泰义 黄智龙 龙汉生 杨勇 | 2007 | 矿物岩石地球化学通报2007，26，z1： | 0 |
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