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1Revealing the Catalytic Conversion via in Situ Characterization for Lithium–Sulfur Batteries显示文摘Probing effective strategies to accelerate the transformation of sulfur species and alleviate the accumulation of lithium polysulfides is of profound significance for breaking through the bottlenecks of the intrinsic redox kinetics and shuttle effect of lithium–sulfur batteries(LSBs).Introducing catalysts is regarded as a straightforward approach to reduce the conversion barrier of sulfur species for enhancing the performance of LSBs.However,the catalytic mechanism is elusive due to the time-varying,process-dependent,and enclosed reaction processes.Therefore,monitoring the evolution of catalysts and sulfur species by in situ characterization during the full process of the redox reaction is essential to reveal the kinetics and the mechanism of catalytic conversion,which may promote novel and efficient catalyst design.This review outlines the recent progress of in situ characterization techniques to investigate the catalytic mechanism.We focus on the evaluation of the catalytic effect and clarification of the catalytic mechanism by in situ characterization techniques.In addition,a perspective on improving the in situ characterization methods and linked data analysis are proposed to offer research suggestions in the field.Qinhua Gu Ming Lu Yiqi Cao Bingsen Zhang 2023Renewables2023,1,6:0
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