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1Microstructure and Corrosion Resistance of a Novel AlNiLa Lightweight Medium Entropy Amorphous Alloy Composites显示文摘A new type of lightweight AlNiLa medium entropy amorphous alloy composite ribbons(labled as MEAAC ribbons)were prepared by vacuum arc melting technology and high-speed single roller meltspinning method.The microstructure and thermal stability of MEAAC ribbons were examined using X-ray diffraction,differential scanning calorimeter,and scanning electron microscope.Meanwhile,the hardness and surface roughness of these ribbons were measured by Vickers microhardness tester and atomic force microscope.The potentiodynamic polarization curves and electrochemical impedance spectroscopy(EIS)were applied to investigate the corrosion behavior of these MEAAC ribbons in simulated seawater(3.5wt%NaCl corrosive solution)at room temperature.The results demonstrate that AlNiLa MEAAC ribbons in the as-received state are mainly composed of amorphous phase and intermetallic compounds.The hardness values of all melt-spun ribbons are above 310 HV_(0.1).With the increase of Al content,the linear polarization resistances of four various AlNiLa MEAAC ribbons are negligibly different numerically.It is also found that Al_(45)Ni_(27.5)La_(27.5) MEAAC ribbons have the most positive corrosion potential and the smallest corrosion current density at the same time;hence it may be a kind of potential material for metal surface protection in harsh ocean environment.张舒研 ZHANG Zhibin 高洋洋 WANG Xin SHEN Baolong 梁秀兵 2022Journal of Wuhan University of Technology(Materials Science)2022,37,6:0
2铸态AlCoCrFeNi_(2.1)共晶高熵合金的拉伸断裂机理显示文摘对铸态AlCoCrFeNi_(2.1)共晶高熵合金的拉伸强度、压缩强度以及折弯强度进行了测试和分析,同时通过原位拉伸实验对其断裂机理进行分析。结果表明:铸态AlCoCrFeNi_(2.1)共晶高熵合金表现出优异的力学性能,其拉伸强度为1005 MPa,断裂应变为15.4%。合金的拉伸断裂形式为脆性断裂加韧性断裂的混合断裂模式,体心立方相B2发生脆性穿晶断裂形成解理面,面心立方相产生塑性变形,微孔不断汇聚长大最终断裂从而形成塑性断裂的韧窝形貌。通过原位拉伸实验,发现在单轴拉应力作用下,面心立方相首先产生塑性变形,而体心立方相不发生塑性变形,仅仅储存大量内应力,之后在体心立方相薄弱区形成微裂纹释放应力;伴随载荷持续增大在裂纹尖端产生应力集中效应,促使该裂纹不断扩展,同时又有新的微裂纹在附近产生;继续增大载荷微裂纹逐渐融合,形成主裂纹,伴随主裂纹扩展同时形成新的微裂纹;形成“生成微裂纹-扩展-聚合-形成主裂纹-进一步扩展”的循环,直至最终断裂。焦世舜 汪佐瑾 周珍珍 曹睿 2022材料热处理学报2022,43,11:0
3(Ti_(35)Zr_(40)Nb_(25))_(100-x)Al_(x)(x=0,5,10,15,20)高熵合金相组成、组织和力学性能显示文摘难熔高熵合金主要由难熔金属元素组成,其熔点通常高于1800℃,且具有高热稳定性和优异抗高温软化能力,在高温领域具有巨大的应用潜力,但是高密度导致的比强度不足和室温脆性等缺点成为其应用的阻碍。本文设计并制备了系列新型非等原子比(Ti_(35)Zr_(40)Nb_(25))_(100-x)Al_(x)(x=0,5,10,15,20)轻质难熔高熵合金,研究了Al含量对相组成、组织和力学性能的影响。X射线衍射分析表明,随着Al含量的增加,合金的相结构由无序BCC转变为有序B2。五种铸态合金具有类似的组织形貌,铸锭边缘存在一个沿着冷却方向生长的细长枝晶区域,铸锭中心区域则主要为等轴枝晶。能谱分析表明Nb元素在枝晶干偏聚,Al和Zr元素则富集在枝晶间,这是由Nb的高熔点以及Al和Zr的强键合共同决定的。室温压缩实验发现Al含量的增加导致合金的屈服强度和抗压强度均逐渐提升,但没有降低室温塑性,所有合金的室温压缩断裂应变均超过50%。曹前 蔚鸾翀 李基民 叶丰 刘斌斌 2024材料工程2024,52,1:0
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