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| 1 | An efficient visible-light photocatalyst for CO2 reduction fabricated by cobalt porphyrin and graphitic carbon nitride via covalent bonding显示文摘Nanoparticle photosensitizers possess technical advantages for photocatalytic reactions due to enhanced light harvesting and efficient charge transport.Here we report synthesis of semiconductor nanoparticles through covalent coupling and assembly of metalloporphyrin with condensed carbon nitride.The resultant nanoparticles consist of light harvesting component from the condensed carbon nitride and photocatalytic sites from the metalloporphyrins.This synergetic particle system effectively initiates efficient charge separation and transport and exhibits excellent photocatalytic activity for CO2 reduction.The CO production rate can reach up to 57μmol/(g·h)with a selectivity of 79%over competing H2 evolution.Controlled experiments demonstrate that the combination of light harvesting with photocatalytic activity via covalent assembly is crucial for the high photocatalytic activity.Due to effective charge separation and transfer,the resultant nanoparticle photocatalysts show exceptional photo stability against photo-corrosion under light irradiation,enabling for long-term utilization.This research opens a new way for the development of stable,effective nanoparticle photocatalysts using naturally abundant porphyrin pigments. | Shufang Tian Sudi Chen Xitong Ren Yaoqing Hu Haiyan Hu Jiajie Sun Feng Bai | 2020 | Nano Research2020，13，10： | 9 |
| 2 | Bottom-up fabrication of graphitic carbon nitride nanosheets modified with porphyrin via covalent bonding for photocatalytic H2 evolution显示文摘In order to broaden the absorption range of graphitic carbon nitride,one of the common methods is to couple the well-known photosensitizer porphyrin with graphitic carbon nitride through van der Waals weak in teractions.To date,to combine porphyrin with graphitic carbon nitridethrough covalent in teractions has not been settled.In this work,through rational molecular design,we successfully in corporated porphyrininto the matrixes of graphitic carbon nitride by covale nt bonding via on expot thermal copolymerization.The resulta nt material not only can wide nthe absorption range but also possess the enlarged specific surface area and construction intramolecular heterojunctions which can contributeto improve electron-holes separation efficiency.The resultant photocatalyst exhibited enhanced H2 production rate(7.6 mmol·g^-1·h^-1)and withthe apparent quantum efficiency(AQE)of 13.3%at 450 nm.At the same time,this method opens a way to fabricate graphitic carb on nitridenano sheets via bottom-up strategy. | Shufang Tian Sudi Chen Xitong Ren Ronghui Cao Haiyan Hu Feng Bai | 2019 | Nano Research2019，12，12： | 8 |
| 3 | A hierarchical heterostructure of CdS QDs confined on 3D ZnIn_(2)S_(4) with boosted charge transfer for photocatalytic CO_(2) reduction显示文摘Metal sulfide based materials as photocatalysts for energy conversion are essential to produce value-added chemical fuels,but their intrinsically slow carrier dynamics and low activity are yet to be resolved.Herein,we developed a unique heterogeneously nanostructured ZnIn_(2)S_(4)-CdS heterostructure that involves zero-dimensional(0D)CdS quantum dots uniformly confined on three-dimensional(3D)ZnIn_(2)S_(4)nanoflowers,which achieves an excellent catalytic performance of CO_(2) photoconversion under visible-light irradiation.The obtained hierarchical heterostructure can significantly enhance the light harvesting,shorten the migration distance of carriers,and obviously accelerate the transport of electrons.As evidenced by the ultrafast transient absorption spectroscopy,the formed interface can effectively facilitate charge separation and transport.This work opens up a new avenue to carefully design the elaborate heterostructures for achieving optimal charge separation efficiency by lowering interfacial kinetic barriers and energy losses at the interface. | Zezhou Zhu Xiaoxia Li Yunteng Qu Fangyao Zhou Zhiyuan Wang Wenyu Wang Changming Zhao Huijuan Wang Liqiang Li Yagang Yao Qun Zhang Yuen Wu | 2021 | Nano Research2021，14，1： | 6 |
| 4 | Modulating the photoelectrons of g-C3N4 via coupling MgTi2O5 as appropriate platform for visible-light-driven photocatalytic solar energy conversion显示文摘Graphitic carbon nitride (g-C3N4) has become an attractive visible-light-responsive photocatalyst because of its semiconductor polymer compositions and easy-modulated band structure. However, the bulk g-C3N4 photocatalyst has the low separation efficiency of photogenerated carriers and unsatisfied surface catalytic performance, which leads to poor photocatalytic performance. As for this, MgTi2O5 with high chemical stability, wide band gap and negative conduction band was used as a suitable platform for coupling with g-C3N4 to enhance charge separation and promoted the photoactivity. Different from common approaches, here, we propose an innovative method to construct g-C3N4/MgTi2O5 nanocomposites featuring “0 + 1 >1' magnification effect to improve g-C3N4 photocatalytic performance under visible light irradiation. Additionally, compositing metal oxides of MgTi2O5 with g-C3N4 has proven to be a proper strategy to accelerate surface catalytic reactions in g-C3N4, and the photoinduced carriers were modulated to maintain thermodynamic equilibrium, which convincingly promotes the photocatalytic activity. The photocatalytic performance of the nanocomposites was measured by hydrogen production and CO2 reduction under visible light. The developed g-C3N4/MgTi2O5 nanocomposites with a 5 wt.% MgTi2O5 exhibits the highest H2 and CO yield under visible light and excellent stability compare to the other MgTi2O5 contents in composites. According to surface photo-voltage spectra, electrochemical CO2 reduction, photoluminescence, etc. The superior performance can be related to an enhanced electron lifetime, the promoted charge transfer and the increased electronic separation property of g-C3N4. Our work provides an approach to overcome the defect of pure g-C3N4, which accesses to composite with the second component matched well. | Jiaxin Shen Yanzhen Li Haoying Zhao Kai Pan Xue Li Yang Qu Guofeng Wang Dingsheng Wang | 2019 | Nano Research2019，12，8： | 6 |
| 5 | g-C_(3)N_(4)/Ag_(2)O复合光催化剂的制备及其近红外光催化性能显示文摘通过简易化学合成法制备了g-C_(3)N_(4)/Ag_(2)O_(p-n)异质结复合光催化剂,利用XRD、XPS、SEM、TEM、DRS等对所制复合材料的物相结构、微观形貌及光学性质进行表征,借助近红外光下催化降解罗丹明B(RhB)试验评价其光催化活性,重点探讨了g-C_(3)N_(4)/Ag_(2)O_(p-n)异质结复合材料的光催化降解机理。结果表明,当g-C_(3)N_(4)、Ag_(2)O质量比为1∶16时,所制g-C_(3)N_(4)/Ag_(2)O复合光催化剂具有最佳的近红外光催化性能且活性稳定;h+和·O-2活性自由基在近红外光催化降解过程中发挥了主要作用。 | 龚洁 赵凤怡 邹曦 陈润泽 陈琪 任大军 张惠灵 | 2021 | 武汉科技大学学报2021，44，2： | 4 |
| 6 | Boosted photoreduction of diluted CO_(2) through oxygen vacancy engineering in NiO nanoplatelets显示文摘Converting carbon dioxide(CO_(2))to diverse value-added products through photocatalysis can validly alleviate the critical issues of greenhouse effect and energy shortages simultaneously.In particular,based on practical considerations,exploring novel catalysts to achieve efficient photoreduction of diluted CO_(2) is necessary and urgent.However,this process is extremely challenging owing to the disturbance of competitive adsorption at low CO_(2) concentration.Herein,we delicately synthesize oxygen vacancy-laden NiO nanoplatelets(r-NiO)via calcination under Ar protection to reduce diluted CO_(2) through visible light irradiation(>400 nm)assisted by a Ru-based photosensitizer.Benefitting from the strongly CO_(2) adsorption energy of oxygen vacancies,which was confirmed by density functional calculations,the r-NiO catalysts exhibit higher activity and selectivity(6.28×10^(3)µmol·h^(−1)·g^(−1);82.11%)for diluted CO_(2)-to-CO conversion than that of the normal NiO(3.94×10^(3)µmol·h^(−1)·g^(−1);65.26%).Besides,the presence of oxygen vacancies can also promote the separation of electron-hole pairs.Our research demonstrates that oxygen vacancies could act as promising candidates for photocatalytic CO_(2) reduction,offering fundamental guidance for the actual photoreduction of diluted CO_(2) in the future. | Weiyi Chen Xueming Liu Bin Han Shujie Liang Hong Deng Zhang Lin | 2021 | Nano Research2021，14，3： | 2 |
| 7 | Construction of ZnIn_(2)S_(4)-CdIn_(2)S_(4) Microspheres for Efficient Photo-catalytic Reduction of CO_(2) with Visible Light显示文摘ZnIn_(2)S_(4) has emerged in water splitting and degradation of dyes due to its good stability and light absorption properties.However,there are still few reports of CO_(2) photoreduction.Herein,we successfully synthesized ZnIn_(2)S_(4) and obtained a series of ZnIn_(2)S_(4)-CdIn_(2)S_(4) heterostructured microspheres through the ion exchange method,and first used them in photocatalytic CO_(2) reduction in noble-metal-free systems.The activity results showed that these ZnIn_(2)S_(4)-CdIn_(2)S_(4) photocatalysts exhibit excellent catalytic activity under visible light,and the best CO yield is as high as 33.57μmol・h^(-1) with a selectivity of 91%.Furthermore,the stability and reusability of ZnIn_(2)S_(4)-CdIn_(2)S_(4) was firmly confirmed by diverse characterizations,including X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray photoelectron spectroscopy(XPS),energy-dispersive X-ray spectroscopy(EDX)and N2 adsorption measurements. | Shitong Han Bifang Li Lijuan Huang Hailing Xi Zhengxin Ding Jinlin Long | 2022 | Chinese Journal of Structural Chemistry2022，41，1： | 2 |
| 8 | Fabrication of magnetically recyclable yolk-shell Fe_(3)O_(4)@TiO_(2) nanosheet/Ag/g-C_(3)N_(4) microspheres for enhanced photocatalytic degradation of organic pollutants显示文摘Herein,we report the fabrication of Fe_(3)O_(4)@TiO_(2) nanosheet/Ag/g-C_(3)N_(4)(Fe_(3)O_(4)@ns-TiO_(2)/Ag/g-C_(3)N_(4))composite photocatalysts with well-designed hierarchical yolk-shell structure.To endow the composites with fascinating features,multiple functional components are perfectly integrated into the definite structure.The photodegradation experiments of organic pollutants revealed a significant enhancement in photocatalytic activity of developed composites as compared to P25,which is mainly due to the synergetic interaction of the tailored three-dimensional(3D)yolk-shell porous nanostructure,extended sunlight response range,and retarded the recombination probability of photogenerated electrons-holes.More importantly,the hybrid samples exhibited superior magnetic properties due to the magnetic component.The excellent magnetic recyclability and reusability of the photocatalysts are verified by the magnetic hysteresis loop and cyclic photocatalytic degradation experiments,which is significant for the green and sustainable applications of photocatalysts.Considering its remarkable photocatalytic performance and expectant magnetic recyclability,the composite photocatalysts are expected to be a promising candidate to dispose of future environmental issues. | Yan Lv Lin Yue Imran Mahmood Khan You Zhou Wenbo Cao Sobia Niazi Zhouping Wang | 2021 | Nano Research2021，14，7： | 1 |
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