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1Hot-corrosion behavior of Cr_2O_3–CNT-coated ASTM-SA213-T22 steel in a molten salt environment at 700°C显示文摘The present work investigates the hot-corrosion behavior of carbon nanotube(CNT)-reinforced chromium oxide coatings on boiler steel in a molten salt(Na_2SO_4–60 wt%V_2O_5) environment at 700°C under cyclic conditions. The coatings were deposited via the high-velocity oxygen fuel process. The uncoated and coated steel samples were subjected to hot corrosion in a silicon tube furnace at 700°C for 50 cycles. The kinetics of the corrosion behavior was analyzed through mass-gain measurements after each cycle. The corrosion products were analyzed by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray analysis techniques. The results revealed that uncoated steel suffered spallation of scale because of the formation of nonprotective Fe_2O_3 scale. The coated steel samples exhibited lower mass gains with better adhesiveness of oxide scale with the steel alloy until the end of exposure. The CNT-reinforced coatings were concluded to provide better corrosion resistance in the hot-corrosion environment because of the uniform dispersion of CNTs in the coating matrix and the formation of protective chromium oxides in the scale.Khushdeep Goyal Hazoor Singh Rakesh Bhatia 2019International Journal of Minerals,Metallurgy and Materials2019,26,3:3
2Microstructure and mechanical properties of Nb–Mo–ZrB_2 composites prepared by hot-pressing sintering显示文摘Nb–Mo–ZrB_2 composites(V(Nb)/V(Mo) = 1) with 15 vol% or 30 vol% of ZrB_2 were fabricated by hot-pressing sintering at 2000°C. The phases, microstructure, and mechanical properties were then investigated. The composites contain Nb-Mo solid solution(denoted as(Nb, Mo)ss hereafter), Zr B, Mo B, and Nb B phases. Compressive strength test results suggest that the strength of Nb–Mo–ZrB_2 composites increases with increasing ZrB_2 content; Nb–Mo–30 vol%ZrB_2 had the highest compressive strength(1905.1 MPa). The improvement in the compressive strength of the Nb–Mo–ZrB_2 composites is mainly attributed to the secondary phase strengthening of the stiffer Zr B phase, solid-solution strengthening of the(Nb, Mo)ss matrix as well as fine-grain strengthening. The fracture toughness decreases with increasing ZrB_2 content. Finally, the fracture modes of the Nb–Mo–ZrB_2 composites are also discussed in detail.yuan gao zong-de liu qi wang yong-tian wang 2018International Journal of Minerals,Metallurgy and Materials2018,25,7:1
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