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    题名 作者 年代 出处 被引量
1光电催化分解水和还原CO2研究进展显示文摘介绍了光电催化(PEC)分解水和还原CO2的基本原理、研究进展。探讨了提高PEC效率的关键策略,主要包括通过能带调控、形貌控制和敏化提高光吸收,通过助催化剂促进表面反应,以及通过构建局部偶极或异质电场、形貌调控和界面修饰促进电荷分离与传输等。丁春梅 姚婷婷 李灿 2020科技导报2020,38,23:2
2Enhanced visible-light photoelectrochemical performance via chemical vapor deposition of Fe2O3 on a WO3 film to form a heterojunction显示文摘A heterojunction photoanode of Fe2O3 loaded on a WO3 film on a fluorine-doped tin oxide substrate(FTO-WO3/Fe2O3)was prepared via a simple hydrothermal and chemical vapor deposition(CVD)growth method.The photoanode showed higher photoelectrochemical(PEC)water-splitting activity than that of the pristine FTO-WO3 under simulated sunlight because of the synergistic effect of Fe2O3 and WO3.The as-synthesized material was characterized by X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),and X-ray photoelectron spectroscopy(XPS).The photocurrent density was estimated by linear sweep voltammetry and further confirmed using intensity-modulated photocurrent spectra.Experiments demonstrated that the coated Fe2O3 enhanced the separation and migration efficiencies of the photoinduced electrons and holes,improving the PEC water-splitting properties.The FTO-WO3/Fe2O3 photoanode showed a 1.25 times enhancement in photocurrent density compared with FTO-WO3.This result suggests that facile chemical vapor deposition growth is an effective way to fabricate heterojunctions and improve the properties of WO3 photoanodes for PEC water-splitting applications.Yi-Fei Zhang Yu-Kun Zhu Chun-Xiao Lv Shou-Juan Lai Wen-Jia Xu Jin Sun Yuan-Yuan Sun Dong-Jiang Yang 2020Rare Metals2020,39,7:2
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